Abstract
The electrophoretic precipitation of a nanodispersed BaTiO3 powder in titanium and silicon alkoxide sol systems instead of organic solvent media has been investigated. The conditions leading to formation of heterophase thin-film coatings with uniformly distributed filler particles in the SiO2 or TiO2 filmforming matrices have been found. The dependence of the BaTiO3 aggregate shape and percolation cluster type on the nature of sols has been studied.
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Hong, J., Song, H.W., Hong, S., and No, K., Fabrication and Investigation of Ultrathin, Smooth Pb(Zr, Ti)O3 Films for Miniaturization of Microelectronic Devices, J. Appl. Phys., 2002, vol. 92, pp. 7434–7441.
Lee J. K., Ku J.-M., Cho C.-R., Lee, Y.K., Shin, S., and Park, Y., Metal-Organic Chemical Vapor Deposition of Pb(Zrx, Ti1−x )O3 Thin Films for High-Density Ferroelectric Random Access Memory Application, J. Semicond. Technol. Sci., 2002, vol. 2, no 3, pp. 205–212.
Vorotilov, K.A. and Sigov, A.S., Ferroelectric Memory Devices: Advanced Technologies and Materials, Nano-Mikrosist. Tekh., 2008, no. 10, pp. 30–42.
Brinker, C.F. and Scherer, G.W., Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing, San Diego, California, United States: Academic, 1990.
Shilova, O., Hashkovsky, S.V., and Kuznetsova, L.A., Sol-Gel Preparation of Coatings for Electrical, Laser, Space Engineering and Power, J. Sol-Gel Sci. Technol., 2003, vol. 26, nos. 1–5, pp. 687–691.
Tarasyuk, E.V., Shilova, O.A., and Khashkovskii, S.V., Zol’-Gel’ Tekhnologiya Polucheniya Steklokeramicheskikh i Gibridnykh Pokrytii (Sol-Gel Technology for Producing Ceramic and Hybrid Coatings) Magnitogorsk: G. I. Nosov Magnitogorsk State Technical University, 2009 [in Russian].
Selmi, F.A. and Amarakoon, V.R.W., Sol-Gel Coating of Powders for Processing Electronic Ceramics, J. Am. Ceram. Soc., 1988, vol. 71, no. 11, pp. 934–937.
Khamova, T.V., Shilova, O.A., and Khashkovskii, S.V., The Sol-Gel Method for Forming Silica Coating on the Surface of Aluminum Oxide Powder, Tekh. Tekhnol. Silik., 2006, vol. 13, no. 3, pp. 17–31.
Zhuravlev, G.I., Avgustinnik, A.I., and Vigdergauz, V.S., Effect of Dispersion of the Solid Phase on Its Electrophoretic Deposition from Suspensions, Zh. Prikl. Khim. (Leningrad), 1963, vol. 36, no. 8, pp. 1650–1656.
Zhuravlev, G.I., Avgustinnik, A.I., and Vigdergauz, V.S., The Effect of Electrochemical Processes on the Deposition of the Dispersed Phase during Electrophoresis, Kolloidn. Zh., 1966, vol. 28, no. 4, pp. 510–514.
Deinega, Yu.F. and Ul’berg, Z.R., Elektroforeticheskie Kompositsionnye Pokrytiya (Electrophoretic Composite Coatings), Moscow: Khimiya, 1989 [in Russian].
Fukada, Y., Nagarajan, N., Mekky, W., Bao, Y., Kim, H.-S., and Nicholson, P.S., Electrophoretic Deposition-Mechanisms, and Materials, J. Mater. Sci., 2004, vol. 39, pp. 787–801.
Ivanov, V.V., Kotov, Yu.A., Lipilin, L.S., Safronov, A.P., Nikonov, A.V., Kalinina, E.G., Rempel’, A.A., Timoshenkova, O.R., and Zayats, S.V., Electrophoretic Forming a Thin Film of Electrolyte on the Cathode Carrier Solid Oxide Fuel Cells, Altern. Energ. Ekol., 2008, vol. 66, no. 10, pp. 36–50.
Ragulya, A.V., Skorokhod, V.V., and Polotai, A.V., Synthesis and Sintering of Nanocrystalline Barium Titanate Powder under Nonisothermal Conditions: VI. Structure, Grain Boundaries and Dielectric Properties of Barium Titanate Obtained by Different Methods of Sintering, Poroshk. Metall. (Kiev), 2001, nos. 1–2, pp. 32–43.
Polotai, A.V., Ragulya, A.V., and Randall, C.A., The XRD and IR Study of the Barium Titanate Nano-Powder Obtained via Oxalate Route, Ferroelectrics, 2004, vol. 298, pp. 243–251.
Maksimov, A.I., Moshnikov, V.A., Tairov, Yu.M., and Shilova, O.A., Osnovy zol’-gel’ tekhnologii nanokompozitov (Fundamentals of Sol-Gel Processing of Nanocomposites), St. Petersburg: Elmor, 2007 [in Russian].
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Original Russian Text © O.A. Shilova, S.V. Hashkovsky, T.V. Khamova, K.E. Pugachev, 2011, published in Fizika i Khimiya Stekla.
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Shilova, O.A., Hashkovsky, S.V., Khamova, T.V. et al. Electrophoresis in the sol-gel formation of heterophase thin-film coatings. Glass Phys Chem 37, 545–548 (2011). https://doi.org/10.1134/S1087659611050130
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DOI: https://doi.org/10.1134/S1087659611050130