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A study of the surface and luminescence properties of ZnS : Mn2+ nanosized phosphors

  • Proceedings of the First All-Russian Conference “Sol-Gel Synthesis and Study of Inorganic Compounds, Hybrid Functional Materials, and Disperse Systems” (St. Petersburg, Russia, November 22–24, 2010)
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Abstract

The influence of the stabilizer and thermal treatment on the luminescence and surface properties of ZnS: Mn2+ nanosized phosphors has been studied. It has been found that ammonium polyacrylate is the optimal stabilizer for the use in the preparation of phosphors with nanoparticles that exhibits the highest brightness without applying thermal treatment. Analysis of the correlation between the luminescence spectral bands and the content of active surface adsorption sites has demonstrated that the model of active sites previously developed for the surface of zinc sulfide phosphors with large particles can also be used for nanosized phosphors.

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References

  1. Yu, J., Liu, H., Wang, Y., Fernandes, F.E., and Jia., W., Optical Properties of ZnS: Mn2+ Nanoparticles in Polymer Films, J. Lumin., 1998, nos. 76–77, pp. 252–255.

  2. Kezuka, T., Konishi, M., Isobe, T., and Senna, M., Preparation and Properties of Nanocrystalline ZnS: Mn-Polymer Composite Films, J. Lumin., 2000, nos. 87–89, pp. 418–420.

  3. Konishi, M., Isobe, T., and Senna, M., Enhancement of Photoluminescence of ZnS: Mn Nano-Crystals, J. Lumin., 2001, no. 93, pp. 1–8.

  4. Bol, A.A. and Meijerink, A., Long-Lived Mn2+ Emission in Nano-Crystalline ZnS: Mn2+, Phys. Rev. B: Condens. Matter, 1998, vol. 58, no. 24, pp. R15997–R16000.

    Article  CAS  Google Scholar 

  5. Tanabe, K., Solid Acids and Bases: Their Catalytic Properties, New York: Academic, 1970. Translated under the title Tverdye kisloty i osnovaniya, Moscow: Mir, 1973.

    Google Scholar 

  6. Nechiporenko, A.P., Donor-Acceptor Surface Properties of Oxides and Chalcogenides, Extended Abstract of Doctoral Dissertation, St. Petersburg State Institute of Technology (Technical University), St. Petersburg, 1995.

    Google Scholar 

  7. Sychov, M.M., Bakhmetyev, V.V., Nakanishi, Y., Mjakin, S.V., Havanova, L.V., Cheremisina, O.A., and Korsakov, V.G., Surface Properties of ZnS and AC Powder Electroluminescent Phosphors, J. Soc. Inf. Disp., 2003, vol. 11, no. 1, pp. 33–38.

    Article  Google Scholar 

  8. Sychov, M.M., Mjakin, S.V., Nakanishi, Y., Korsakov, V.G., Vasiljeva, I.V., Bakhmetyev, V.V., Solovjeva, O.V., and Komarov, E.V., Study of Active Surface Centers in Electroluminescent ZnS: Cu, Cl Phosphors, Appl. Surf. Sci., 2005, vol. 244, nos. 1–4, pp. 461–464.

    Article  CAS  Google Scholar 

  9. Mjakin, S.V., Sychov, M.M., Vasil’eva, I.V., Korsakov, V.G., Maslennikova, L.L., Sychova, A.M., Abu-Khasan, M.S., Yakimova, N.I., and Makarov, A.V., Elektronnoluchevoe modifitsirovanie funktsional’nykh materialov (Electron-Beam Modification of Functional Materials), St. Petersburg: Petersburg State Transport University, 2006 [in Russian].

    Google Scholar 

  10. Bakhmetyev, V.V., Sychov, M.M., and Korsakov, V.G., A Model of Active Acid-Base Surface Sites for Zinc Sulfide Electroluminescent Phosphors Russ. J. Appl. Chem., 2010, vol. 83, no. 11, pp. 1903–1910.

    Article  Google Scholar 

  11. Abyzov, A.M., Rentgenodifraktsionnyi analiz polikristallicheskikh veshchestv na minidifraktometre “Difrei”: Uchebnoe posobie (X-Ray Diffraction Analysis of Polycrystalline Materials by Mini X-Ray Diffractometer “Difray”: A Textbook), St. Petersburg: St. Petersburg State Institute of Technology (Technical University), 2008 [in Russian].

    Google Scholar 

  12. Kargin, N.I., Mikhnev, L.V., and Gusev, A.S., On the Complex Nature of the Luminescence of ZnS: Mn Luminophor, Sb. Nauchn. Tr. Sev.-Kavk. Gos. Tekh. Univ., Ser. Fiz-Khim., 2002, no. 6, pp. 3–4.

  13. Miloslavskii, A.G. and Suntsov, N.V., Defect Structure and Luminescence Centers of Zinc Sulfide Luminophors, Fiz. Tekh. Vys. Davlenii (Donetsk), 1997, vol. 7, no. 2, pp. 94–103.

    Google Scholar 

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Authors and Affiliations

  1. St. Petersburg State Institute of Technology (Technical University), Moskovskii pr. 26, St. Petersburg, 190013, Russia

    V. V. Bakhmetyev, S. V. Mjakin, V. G. Korsakov, A. M. Abyzov & M. M. Sychov

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  1. V. V. Bakhmetyev
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  2. S. V. Mjakin
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  3. V. G. Korsakov
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  4. A. M. Abyzov
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  5. M. M. Sychov
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Correspondence to V. V. Bakhmetyev.

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Original Russian Text © V.V. Bakhmetyev, S.V. Mjakin, V.G. Korsakov, A.M. Abyzov, M.M. Sychov, 2011, published in Fizika i Khimiya Stekla.

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Bakhmetyev, V.V., Mjakin, S.V., Korsakov, V.G. et al. A study of the surface and luminescence properties of ZnS : Mn2+ nanosized phosphors. Glass Phys Chem 37, 549–554 (2011). https://doi.org/10.1134/S1087659611050026

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  • DOI: https://doi.org/10.1134/S1087659611050026

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