Abstract
In the present paper, we report the applicability of Meyer-Neldel rule for pre-exponential factor of non-isothermal crystallization in Se70Te30 and Se70Te28M2 (M = Ag, Sb, Zn) glasses using DSC technique. We have observed strong correlation between pre-exponential factor K 0 and activation energy of non-isothermal crystallization E c for the present glasses.
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Mehta, N., Chalcogenide Glasses in Electronics and Optoelectronics: A Review on Their Applications, J. Sci. Ind. Res., 2006, vol. 65, pp. 777–786.
Surinach, S., Baro, M.D., Clavaguera-Mora, M.T., and Clavaguera, N., Glass Formation and Crystallization in the GeSe2-Sb2Te3 System, J. Mater. Sci., 1984, vol. 19, pp. 3005–3012.
Hu, L. and Juang, Z., New Criterion for Crystallization of Glass, J. Chin. Ceram. Soc., 1990, vol. 18, pp. 315–321.
Hruby, A., Evaluation of Glass-Forming Tendency by Means of DTA, Czech. J. Phys. B, 1972, vol. 22, pp. 1187–1193.
Barreda, D.H., Vazquez, J., Lopez-Alemany, P.L., Villares, P., and Jimenez-Garay, R., A Comparative Study on the Glass-Forming Ability of Some Alloys in the Sb-As-Se System by Differential Scanning Calorimetry, J. Phys. Chem. Solids, 2005, vol. 66, pp. 1783–1787.
Meyer, W. and Neldel, H., Uber die Beziehungen zwischen der Energiekonstanten e und der Mengenkonstanten a in der Leitwerts-Temperaturformel bei oxydischen Halbleitern’, Z. Tech. Phys., 1937, vol. 18, pp. 588–593.
Deren, J., Podgorecka, A., and Burzyk, J., Physicochemical and Catalytic Properties of the System Chromium Oxides-Oxygen-Water, J. Catal., 1963, vol. 2, pp. 161–175.
Ahuja, L.D. and Brar, A.S., Physico-Chemical Characteristics of Cobalt Oxides and Their Catalytic Activities, J. Colloid Interface Sci., 1975, vol. 50, pp. 197–207.
Dosdale, T. and Brook, R.J., The Relationship between Measured Activation Enthalpy and Pre-Exponential Factor: Rate Processes in Ionic Crystals in the Intrinsic-Extrinsic Region, Solid State Ionics, 1983, vol. 8, pp. 297–304.
Metselaar, R. and Oversluizen, G., The Meyer-Neldel Rule in Semiconductors, J. Solid State Chem., 1984, vol. 55, pp. 320–326.
Niemantsverdriet, J.W., Markert, K., and Wandelt, K., The Compensation Effect and the Manifestation of Lateral Interactions in Thermal Desorption Spectroscopy, Appl. Surf. Sci., 1988, vol. 31, pp. 211–219.
Bogusz, W., Kony, D.E., and Krok, F., Application of the Meyer-Neldel Rule to the Electrical Conductivity of Nasicon, Mater. Sci. Eng., B., 1992, vol. 15, pp. 169–172.
Bond, G.C., Kinetics of Alkane Reactions on Metal Catalysts: Activation Energies and the Compensation Effect, Catal. Today, 1999, vol. 49, pp. 41–48.
Augis, J.A. and Bennett, J.E., Calculation of the Avrami Parameters for Heterogeneous Solid State Reactions Using a Modification of the Kissinger Method, J. Therm. Anal., 1978, vol. 13, pp. 283–292.
Johnson, W.A. and Mehl, R.F., Reaction Kinetics of Nucleation and Growth, Trans. Am. Inst. Min., Metall. Pet. Eng., 1939, vol. 135, pp. 416–442.
Avrami, M., Kinetics of Phase Change I, J. Phys. Chem., 1939, vol. 7, pp. 1103–1112.
Avrami, M., Kinetics of Phase Change II, J. Phys. Chem., 1940, vol. 8, pp. 212–224.
Koga, N. and Sestak, J., Kinetic Compensation Effect as a Mathematical Consequence of the Exponential Rate Constant, Thermochim. Acta, 1991, vol. 182, pp. 201–208.
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Original Russian Text © S. Saraswat, S.S.S. Kushwaha, 2009, published in Fizika i Khimiya Stekla.
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Saraswat, S., Kushwaha, S.S.S. Observation of Meyer-Neldel relation for non-isothermal crystallization in Se70Te30 and Se70Te28M2 (M = Ag, Sb, Zn) glasses. Glass Phys Chem 35, 290–294 (2009). https://doi.org/10.1134/S1087659609030080
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DOI: https://doi.org/10.1134/S1087659609030080