Abstract
The absorption edge spectra of vitreous alloys in the As-S-Se system are measured in the temperature range 77–300 K. The parameters of the fundamental absorption edge and the electron-phonon interaction in As40S60 − x Se x (x = 0–40) glasses are determined, and the influence of the compositional disorder on these parameters is investigated. The contributions of the static structural and temperature disorders to the smearing of the fundamental absorption edge of the alloys under study are evaluated.
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Feltz, A., Amorphe und glasartige anorganische Festkorper, Berlin: Akademie, 1983. Translated under the title Amorfnye i stekloobraznye neorganicheskie tverdye tela, Moscow: Mir, 1986 [in German and in Russian].
Shvarts, K.K., Fizika opticheskoi zapisi v dielektrikakh i poluprovodnikakh (Physics of Optical Recording in Dielectrics and Semiconductors), Riga: Zinatne, 1986 [in Russian].
Semak, D.G., Rizak, V.M., and Rizak, I.M., Foto-termostrukturnye prevrashcheniya khal’kogenidov (Photo-Thermostructural Transformations of Chalcogenides) Uzhgorod: Zakarpattya, 1999 [in Ukrainian].
Elektronnye yavleniya v khal’kogenidnykh stekloobraznykh poluprovodnikakh (Electronic Phenomena in Vitreous Chalcogenide Semiconductors), Tsendin, K.D., Ed., St. Petersburg: Nauka, 1996.
Popescu, M.A., Non-Crystalline Chalcogenides, Dordrecht: Kluwer, 2000.
Sanghera, J.S. and Aggarwal, I.D., Active and Passive Chalcogenide Glass Optical Fibers for IR Applications, J. Non-Gryst. Solids, 1999, vols. 256–257, pp. 6–16.
Zakery, A. and Elliot, S.R., Optical Properties and Applications of Chalcogenide Glasses: A Review, J. Non-Gryst. Solids, 2003, vol. 330, pp. 1–12.
Teteris, J. and Reifelde, M., Application of Amorphous Chalcogenide Semiconductor Thin Films in Optical Recording Technologies, J. Optoelectron. Adv. Mater., 2003, vol. 5, no. 5, pp. 1355–1360.
Pedlikova, J., Zavadil, J., Prochazkova, O., and Lezal, D., Special Glasses for Infrared Applications, J. Optoelectron. Adv. Mater., 2007, vol. 9, no. 6, pp. 1679–1682.
Amosova, L.P. and Chaika, A.N., Optically Addressed As50Se50-Liquid Crystal Structure Highly Sensitive to He-Ne Laser Radiation, Pis’ma Zh. Tekh. Fiz., 2007, vol. 33, no. 6, pp. 56–62 [Tech. Phys. Lett. (Engl. transl.), 2007, vol. 33, no. 3, pp. 255–257].
Singh, J. and Shimakawa, K., Advances in Amorphous Semiconductors, London: Taylor and Fransis, 2004.
Non-Crystalline Materials for Optoelectronics, Lucovsky, G. and Popescu, M., Eds., Bucharest: National Institute of Optoelectronics (INOE), 2004.
Shpak, A.P. and Rubish, V.M., Stekloobrazovanie i svoistva splavov v khal’kogenidnykh sistemakh na osnove mysh’yaka i sur’my (Glass Formation and Properties of Alloys in Chalcogenide systems Based on Arsenic and Antimony) Kiev: Kurdyumov Institute of Metal Physics of the National Academy of Sciences of Ukraine, 2006 [in Russian].
Shpak, I.I., Studenyak, I.P., Semak, D.G., Kranjcec, M., Rubish, V.V., and Rubish, V.V., Composition Dependence and Interrelation between Optical-Refractometric and Thermo-Optical Parameters of Vitreous Alloys (As2S3)100 − X (As2Se3)X, Ukr. Fiz. Zh., 2007, vol. 52, no. 4, pp. 367–371.
Shpak, I.I., Kranjcec, M., and Studenyak, I.P., Optical Constants of Electron-Irradiated As2S3 Chalcogenide Glasses, J. Optoelectron. Adv. Mater., 2005, vol. 5, no. 5, pp. 2017–2020.
Vainshtein, I.A., Zatsepin, A.F., and Kortov, V.S., Specific Features of the Urbach Rule Manifestation in Vitreous Materials, Fiz. Khim. Stekla, 1999, vol. 25, no. 1, pp. 70–81 [Glass Phys. Chem. (Engl. transl.), 1999, vol. 25, no. 1, pp. 67–74].
Vainshtein, I.A., Zatsepin, A.F., and Kortov, V.S., Applicability of the Empirical Varshni Relation for the Temperature Dependence of the Width of the Band Gap, Fiz. Tverd. Tela (St. Petersburg), 1999, vol. 41, no. 6, pp. 994–998 [Phys. Solid State (Engl. transl.), 1999, vol. 41, no. 6, pp. 905–908].
Gody, G.D., Tiedje, T., Abeles, B., Brooks, B., and Goldstain, Y., Disorder and the Optical-Absorption Edge of Hydrogenated Amorphous Silicon, Phys. Rev. Lett., 1981, vol. 47, no. 20, pp. 1480–1483.
Ravindra, N.M. and Demichelis, F., Gody Disorder: Absorption-Edge Relationships in Hydrogenated Amorphous Silicon, Phys. Rev. B: Condens. Matter, 1985, vol. 32, no. 10, pp. 6591–6595.
Ihm, J., Urbach Tails and Structure of Chalcogenide Glasses, J. Phys. C: Solid State Phys., 1985, vol. 18, no. 4, pp. 4741–4751.
O’Leary, S.K., Zukotynski, S., and Perz, J.M., Optical Absorption in Amorphous Semiconductors, Phys. Rev. B: Condens. Matter, 1995, vol. 51, no. 11, pp. 7795–7797.
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Original Russian Text © M.M. Pop, I.I. Shpak, M.I. Kozak, D.G. Semak, 2009, published in Fizika i Khimiya Stekla.
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Pop, M.M., Shpak, I.I., Kozak, M.I. et al. Optical absorption and disorder in the As40S60 − x Se x vitreous alloys. Glass Phys Chem 35, 158–162 (2009). https://doi.org/10.1134/S1087659609020060
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DOI: https://doi.org/10.1134/S1087659609020060