Abstract
A technique is proposed for introducing microdoses (10−5–10−10 g) of germanium and indium metals into semiconductor compounds by coulometric titration in a solid electrolyte cell. The solid electrolytes that are reversible with respect to germanium cations (the GeSe-GeI2 system containing 5 mol % GeI2) and indium cations (the InCl3-MgCl2 system containing 15 mol % MgCl2, the InCl3-CdCl2 system containing 1.5 mol % CdCl2, and the In2S3-InCl3 system containing 5 mol % InCl3) are chosen, and their electric transport properties are characterized. The optimum conditions for electrochemical doping (temperature, current density), under which the current efficiency reaches 90–100%, are determined. The doping with germanium and indium is performed for nonstoichiometric compounds, such as lead monotelluride, indium sulfide, and ternary chalcogenide spinel Cd1 ± δCr2Se4. The doping efficiency is controlled by measuring the electromotive force of the corresponding electrochemical cells and the Hall effect, as well as using the electrical conductivity method. The solid electrolytes that are reversible with respect to indium are used to determine the standard Gibbs energies of formation of a number of indium-containing semiconductors.
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Leushina, A.P., Kolesnikova, L.A., Makhanova, E.V., and Zlomanov, V.P., Thermodynamics of Binary and Ternary Copper-, Cadmium, and Indium-Containing Semiconducting Phases: An Electrochemical Study, Elektrokhimiya, 2005, vol. 41, no. 6, pp. 721–727 [Russ. J. Elektrochem. (Engl. transl.), 2005, vol. 41, no. 6, pp. 639–645].
Danilov, D.N., Leushina, A.P., and Zlomanov, V.P., T-x Diagram and Transport Properties of the GeSe-GeI2 Solid Electrolyte, Zh. Fiz. Khim., 2006, vol. 80, no. 11, pp. 2063–2067 [Russ. J. Phys. Chem. (Engl. transl.), 2006, vol. 80, no. 11, pp. 1837–1841].
Leushina, A.P., Danilov, D.N., and Zlomanov, V.P., Use of Solid Electrolyte GeSe-GeI2 for Electrochemical Doping with Germanium, Elektrokhimiya, 2007, vol. 43, no. 4, pp. 504–507 [Russ. J. Elektrochem. (Engl. transl.), 2007, vol. 43, no. 4, pp. 479–482].
Leushina, A.P., Makhanova, E.V., and Danilov, D.N., Selecting Indium-Containing Systems as Solid Electrolytes, Elektrokhimiya, 2007, vol. 43, no. 6, pp. 655–659 [Russ. J. Elektrochem. (Engl. transl.), 2007, vol. 43, no. 6, pp. 633–637].
Shelimova, L.E., Tomashik, V.N., and Grytsiv, V.I., Diagrammy sostoyaniya v poluprovodnikovom materialovedenii: Sistemy na osnove khal’kogenidov Si, Ge, Sn, Pb (Phase Diagrams in Semiconductor Materials Science: Systems based on the Si, Ge, Sn, and Pb Chalcogenides), Moscow: Nauka, 1991 [in Russian].
Massimo, M. and Cadoff, I.B., Pb1 − x GexTe Solubilities, Electrical and Optical Properties, J. Electron. Mater., 1976, vol. 3, pp. 601–610.
Ravel, B., Cockayne, E., Newville, M., and Rabe, K.M., A Combined EXAFS and First Principles Theory Study of Pb1 − x GexTe, Phys. Rev. B: Condens. Matter, 1999, vol. 60, pp. 14632–14642.
Abakumova, T.A., Yashina, L.V., Tananaeva, O.I., and Zlomanov, V.P., Ge as a Donor in PbTe, Neorg. Mater., 1994, vol. 30, pp. 1121–1127.
Yashina, L.V., Neudachina, V.S., Tikhonov, E.V., Shtanov, V.I., Molodtsov, S.L., Poyguine, M., Surface Core-Level Shift and Impurity Charge States of (100) PbTe(X) Surface (X = Ge, Ga), BESSY Annu. Rep., 2003, pp. 431–440.
Zyubin, A.S., Dedyulin, S.N., Shtanov, V.I., and Yashina, L.V., Simulation of the Geometric and Electronic Structures and Properties of Extrinsic Defects Involving Germanium in Lead Telluride, Zh. Neorg. Khim., 2007, vol. 52, no. 1, pp. 88–96 [Russ. J. Inorg. Chem. (Engl. transl.), 2007, vol. 52, no. 1, pp. 83–91].
Termicheskie konstanty veshchestv (Thermal Constants of Compounds), Moscow: VINITI, 1970–1971, Vol. 4, Parts 1, 2 [in Russian].
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Original Russian Text © A.P. Leushina, D.N. Danilov, E.V. Zyablitseva, 2008, published in Fizika i Khimiya Stekla.
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Leushina, A.P., Danilov, D.N. & Zyablitseva, E.V. Introduction of microdoses of germanium and indium dopants into the bulk and surface layers of semiconductor materials. Glass Phys Chem 34, 716–723 (2008). https://doi.org/10.1134/S1087659608060096
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DOI: https://doi.org/10.1134/S1087659608060096