Abstract
The kinetics of the interaction of high-melting titanium compounds with glass melts is investigated with the aim of choosing the optimum conditions for the production of refractory glass-ceramic coatings for the titanium protection and predicting their service reliability. The rate constants of interfacial reactions are determined, and their mechanisms are established. It is revealed that the TiB2 and TiSi2 compounds are extremely stable with respect to the glass melts containing the Al2O3 oxide. The use of these compounds as barrier layers in the design of new glass-ceramic coatings for the titanium protection ensures an increase in the heat resistance when operating in corrosive media.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Sitnikova, A.Ya. and Appen, A.A., Chemically Durable Coatings for Titanium Protection, in Trudy IV Vsesoyuznogo soveshchaniya “Zharostoikie i teplostoikie pokrytiya” (Proceedings of the IV All-Union Conference “Refractory and Heat-Resistant Coatings”), Leningrad: Nauka, 1969, pp. 211–219 [in Russian].
Sitnikova, A.Ya., Appen, A.A., and Fedorov, V.N., Diffusion Chemical Processes at the Interface of Titanium with Silicate Coatings and Melts, in Zashchitnye pokrytiya na metallakh (Protective Coatings on Metals), Kiev, 1974, issue 8, pp. 27–34 [in Russian].
Podor, R., Rapin, C., David, N., and Berthod, P., Titanium Corrosion in Molten Glasses: Part 1. Immersion Test and Corrosion Kinetics, Glass. Sci. Technol., 2004, vol. 77, no. 1, pp. 36–43.
Rapin, C., Podor, R., Michon, S., Berthod, P., and Mathien, S., Titanium Corrosion in Molten Glasses: Part 2. Electrochemical Study and Corrosion Mechanisms, Glass. Sci. Technol., 2004, vol. 77, no. 2, pp. 88–94.
Borisenko, V.A. and Sitnikova, A.Ya., On the Possibility of Producing a Barrier Layer at the Titanium-Silicate Coating Interface, in Trudy XI Vsesoyuznogo soveshchaniya “Temperaturoustoichivye pokrytiya” (Proceedings of the XI All-Union Conference “Temperature-Resistant Coatings”), Leningrad: Nauka, 1985, pp. 77–82 [in Russian].
Kislyi, P.S., Shilo, A.E., and Dovgan’, A.G., Interaction of Silicate Melts with Titanium and Zirconium Diborides, Adgeziya Raspl. Paika Mater., 1982, no. 10, pp. 67–69.
Kislyi, P.S., Shilo, A.E., Dovgan’, A.G., and Kryuchkova, A.R., On the Interaction of Titanium Diborides with Silicate Melts, Adgeziya Raspl. Paika Mater., 1983, no. 11, pp. 43–46.
Dovgan’, A.G., Vashchenko, A.N., Panasyuk, A.D., and Umanskii, A.P., Interaction of Titanium and Zirconium Diborides with Silicate Melts, Poroshk. Metall., 1988, no. 7, pp. 84–88.
Sviridov, S.I., Zhabrev, V.A., and Lopatina, N.P., Kinetics of Interaction of Titanium Diboride with Glass Melts, Fiz. Khim. Stekla, 1991, vol. 17, no. 1, pp. 47–51.
Brown, M.E., Dollimore, D., and Galwey, A.K., in Reactions in the Solid State: Comprehensive Chemical Kinetics, Bamford C.H. and Tipper C.F.H., Eds., Amsterdam: Elsevier, 1980, vol. 22. Translated under the title Reaktsii tverdykha tel, Moscow: Mir, 1983.
Sharp, J.H., Brindley, G.W., and Narahari, B.N., Numerical Data for Some Commonly Used Solid State Reactions Equations, J. Am. Ceram. Soc., 1972, vol. 49, no. 7, pp. 379–382.
Belykh, D.B., Zhabrev, V.A., Zaitsev, S.V., Glushkova, V.B., and Krzhizhanovskaya, V.A., Interaction of Y2O3-Stabilized Cubic ZrO2 with Sodium Silicate and Sodium Aluminosilicate Glass-Forming Melts, Fiz. Khim. Stekla, 2002, vol. 28, no. 1, pp. 54–59 [Glass Phys. Chem. (Engl. transl.), 2002, vol. 28, no. 1, pp. 36–39].
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © S.I. Sviridov, 2008, published in Fizika i Khimiya Stekla.
Rights and permissions
About this article
Cite this article
Sviridov, S.I. Interaction of glass melts with high-melting titanium compounds. Glass Phys Chem 34, 362–368 (2008). https://doi.org/10.1134/S1087659608040044
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1087659608040044