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On the local structure of Cd3+ centers in (BaGeO3)1 − x − y (Al2O3) x (0.45CaF2 · 0.55MgF2) y glasses

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Abstract

A correlation between the 155Gd Mössbauer spectra of the GdAlO3 and Gd3Al5O12 compounds and Gd3+-doped glasses in the (BaGeO3)1 − x − y (Al2O3) x (0.45CaF2 · 0.55MgF2) y system is revealed. The conclusion is drawn that, in the structure of the glasses under investigation, trivalent gadolinium atoms form structural units characteristic of mixed gadolinium and aluminum oxides.

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References

  1. Nemov, S.A., Marchenko, A.V., and Seregin, P.P., Parameters of Luminescence and the Local Structure of Eu3+ Centers in Fluorogermanate Glasses, Fiz. Khim. Stekla, 2008, vol. 34, no. 1, pp. 61–65 [Glass Phys. Chem. (Engl. transl.), 2008, vol. 34, no. 1, pp. 47–49].

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  2. Seregin, P.P., Fizicheskie osnovy messbauerovskoi spektroskopii (Physical Principles of Mössbauer Spectroscopy), St. Petersburg: St. Petersburg State Polytechnical University, 2002 [in Russian].

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Authors and Affiliations

  1. St. Petersburg State Polytechnical University, Politekhnicheskaya ul. 29, St. Petersburg, 195251, Russia

    S. A. Nemov

  2. Herzen Russian State Pedagogical University, nab. Reki Moiki 48, St. Petersburg, 191186, Russia

    A. V. Marchenko & P. P. Seregin

Authors
  1. S. A. Nemov
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  2. A. V. Marchenko
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  3. P. P. Seregin
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Corresponding author

Correspondence to P. P. Seregin.

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Original Russian Text © S.A. Nemov, A.V. Marchenko, P.P. Seregin, 2008, published in Fizika i Khimiya Stekla.

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Nemov, S.A., Marchenko, A.V. & Seregin, P.P. On the local structure of Cd3+ centers in (BaGeO3)1 − x − y (Al2O3) x (0.45CaF2 · 0.55MgF2) y glasses. Glass Phys Chem 34, 343–345 (2008). https://doi.org/10.1134/S1087659608030188

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  • DOI: https://doi.org/10.1134/S1087659608030188

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