Skip to main content
Log in

Influence of superstoichiometric boron on the synthesis of cubic boron nitride

  • Published:
Glass Physics and Chemistry Aims and scope Submit manuscript

Abstract

Initiators of the synthesis of cubic boron nitride in the Mg-B-N and Li-B-N-O systems are compared. The influence of boron not bound in metal boronitrides and metal borates is investigated. It is proposed to distinguish “excess” boron introduced in the elemental form from “active excess” boron formed in the course of chemical transformations of initiators.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Abrasive Material and Preparation Thereof, US Patent No. 2 947 617, June 6, 1958.

  2. A Method for Preparing Cubic Boron Nitride, FRG Patent, No. 3 030 362, August 11, 1980.

  3. A Method for Synthesizing Cubic Boron Nitride, JP Appl. No. 56-140 013, March 31, 1980.

  4. A Method for Producing Transparent Sintered Cubic Boron Nitride, JP Appl. No. 59-57 967, September 27, 1982.

  5. Endo, T., Fukunaga, O., and Iwata, M., Precipitation Mechanism of BN in the Ternary System of B-Mg-N, J. Mater. Sci., 1979, vol. 14, no. 7, pp. 1676–1680.

    Article  CAS  Google Scholar 

  6. Kagamida, M., Kanda, H., Akaishi, M., Nukui, A., Osawa, T., and Yamaoka, S., Crystal Growth of the Cubic Boron Nitride Using Li3BN2 Solvent under High Temperature and Pressure, J. Cryst. Growth, 1989, vol. 94, no. 1, pp. 261–269.

    Article  CAS  Google Scholar 

  7. Elliot, R.P., Constitution of Binary Alloys, New York: McGraw-Hill, 1965. Translated under the title Struktury dvoinykh splavov, Moscow: Metallurgiya, 1970.

    Google Scholar 

  8. Bogdanov, S.P., Role of the Particle Size of Graphite-Like Boron Nitride in Nucleation of Cubic Boron Nitride, Fiz. Khim. Stekla, 2008, vol. 34, no. 2, pp. 200–210 [Glass Phys. Chem. (Engl. transl.), 2008, vol. 34, no. 2, pp. 213–217].

    Google Scholar 

  9. Shipilo, V.B., Shishonok, E.M., Ignatenko, O.V., and Azarko, I.I., Influence of the Synthesis Parameters and Catalytic System of the Growth of Cubic Boron Nitride on the Cathodoluminescence and Electron Paramagnetic Resonance Spectra, in Sbornik dokladov Mezhdunarodnoi nauchnoi konferentsii “Aktual’nye problemy fiziki tverdogo tela (FTT-2005)” (Proceedings of the International Scientific Conference on Important Problems in Solid State Physics), Minsk: Institute of Solid-State and Semiconductor Physics of the National Academy of Sciences of Belarus, 2005, pp. 383–386.

    Google Scholar 

  10. Shipilo, V.B., Ignatenko, O.V., Anichenko, N.G., and Azarko, I.I., Influence of Boron on the Process of Crystallization of Cubic Boron Nitride in the Li3N-BN System, in Sbornik dokladov Mezhdunarodnoi nauchnoi konferentsii “Aktual’nye problemy fiziki tverdogo tela (FTT-2005)” (Proceedings of the International Scientific Conference on Important Problems in Solid State Physics), Minsk: Institute of Solid-State and Semiconductor Physics of the National Academy of Sciences of Belarus, 2005, pp. 406–408 [in Russian].

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. P. Bogdanov.

Additional information

Original Russian Text © S.P. Bogdanov, 2008, published in Fizika i Khimiya Stekla.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bogdanov, S.P. Influence of superstoichiometric boron on the synthesis of cubic boron nitride. Glass Phys Chem 34, 336–339 (2008). https://doi.org/10.1134/S1087659608030164

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1087659608030164

Keywords

Navigation