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Effect of the thermal prehistory of components on the hydration and crystallization of Mg3Si2O5(OH)4 nanotubes under hydrothermal conditions

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Abstract

The influence of the thermal prehistory of precursors on the phase transformations occurring in the MgO-SiO2-H2O(NaOH) system during hydrothermal synthesis of nanotubular magnesium hydrosilicates Mg3Si2O5(OH)4 with a chrysotile structure is investigated by in situ Calvet calorimetry. It is demonstrated that the preliminary dehydration of the initial solid-phase reactants substantially affects the kinetics of their hydration and subsequent formation of nanotubes with a chrysotile structure.

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Authors and Affiliations

  1. Federal State Unitary Enterprise, “Russian Scientific Center Applied Chemistry”, pr. Dobrolubova 14, St. Petersburg, 197198, Russia

    F. Yu. Sharikov

  2. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, nab. Makarova 2, St. Petersburg, 199034, Russia

    E. N. Korytkova & V. V. Gusarov

Authors
  1. F. Yu. Sharikov
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  2. E. N. Korytkova
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  3. V. V. Gusarov
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Original Russian Text © F.Yu. Sharikov, E.N. Korytkova, V.V. Gusarov, 2007, published in Fizika i Khimiya Stekla.

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Sharikov, F.Y., Korytkova, E.N. & Gusarov, V.V. Effect of the thermal prehistory of components on the hydration and crystallization of Mg3Si2O5(OH)4 nanotubes under hydrothermal conditions. Glass Phys Chem 33, 515–520 (2007). https://doi.org/10.1134/S108765960705015X

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  • DOI: https://doi.org/10.1134/S108765960705015X

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