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Sulfide-conducting solid electrolytes for preparation of nonstoichiometric compounds with controlled composition and properties

  • Proceedings of the Topical Meeting of the European Ceramic Society “Structural Chemistry of Partially Ordered Systems, Nanoparticles, and Nanocomposites” (St. Petersburg, Russia, June 27–29, 2006)
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Abstract

The influence of the electrolytic properties of the sulfide-conducting electrolytes CaY2S4, CaPr2S4, and BaSm2S4 on the possibility of performing the electrochemical correction of the composition of nonstoichiometric cadmium and lead sulfides is investigated. The width of the homogeneity region of the CdS and PbS sulfides is estimated in the temperature range 300–400°C. A model of defect formation is proposed.

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Authors and Affiliations

  1. Vyatka State University, ul. Moskovskaya 36, Kirov, 610000, Russia

    E. G. Fominykh, L. A. Kalinina, G. I. Shirokova, Yu. N. Ushakova, T. I. Rychkova & B. A. Ananchenko

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  1. E. G. Fominykh
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  2. L. A. Kalinina
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  3. G. I. Shirokova
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  4. Yu. N. Ushakova
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  5. T. I. Rychkova
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  6. B. A. Ananchenko
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Corresponding author

Correspondence to L. A. Kalinina.

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Original Russian Text © E.G. Fominykh, L.A. Kalinina, G.I. Shirokova, Yu.N. Ushakova, T.I. Rychkova, B.A. Ananchenko, 2007, published in Fizika i Khimiya Stekla.

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Fominykh, E.G., Kalinina, L.A., Shirokova, G.I. et al. Sulfide-conducting solid electrolytes for preparation of nonstoichiometric compounds with controlled composition and properties. Glass Phys Chem 33, 362–368 (2007). https://doi.org/10.1134/S1087659607040104

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  • DOI: https://doi.org/10.1134/S1087659607040104

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