Abstract
The kinetics of the interaction of aluminum oxide and silicon dioxide single crystals with phosphoric acid is investigated under isothermal treatment at temperatures in the range 250–350°C. The probable mechanism of the reactions of Al2O3 and SiO2 with phosphoric acid is considered. The influence of the structure of the Al2O3 and SiO2 oxides on their interaction with phosphoric acid is analyzed.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Golynko-Vol’fson, S.L., Sychev, M.M., Sudakas, L.G., and Skoblo, L.I., Khimicheskie osnovy tekhnologii i primeneniya fosfatnykh svyazok i pokrytii (Chemical Principles of the Technology and Application of Phosphate Binders and Coatings), Leningrad: Khimiya, 1968 [in Russian].
Elektroizolyatsionnye materialy vysokoi nagrevostoikosti (Heat-Resistant Electrically Insulating Materials), Asnovich, E.Z., Zabyrin, K.I., Kolganov, V.A., and Tareev, B.M., Eds., Moscow: Energiya, 1979 [in Russian].
Kopeikin, V.A., Klement’eva, V.S., and Krasnyi, B.L., Ogneupornye rastvory na fosfatnykh svyazuyushchikh (Refractory Solutions Based on Phosphate Binders), Moscow: Metallurgiya, 1986 [in Russian].
Kopeikin, V.A., Petrova, A.P., and Rashkovan, I.L., Materialy na osnove metallofosfatov (Materials Based on Metal Phosphates), Moscow: Khimiya, 1976 [in Russian].
Kopeikin, V.A. and Rashkovan, I.L., Processes of Formation of Phosphate Materials, Neorg. Mater., 1979, vol. 15, no. 6, pp. 980–984.
Klyucharov, Ya.V. and Skoblo, L.I., On the Composition of Curing Products of Aluminophosphate Binders in Refractory Corundum Materials, Zh. Prikl. Khim. (Leningrad), 1965, vol. 38, no. 3, pp. 520–526.
Gitzen, W.H. and Hart, L.D., Phosphate-Bonded Alumina Castables: Some Properties and Applications, Am. Ceram. Soc. Bull., 1956, vol. 35, no. 6, pp. 217–223.
Latutova, M.N., Preparation and Application of Materials Based on Aluminum Phosphates, Extended Abstract of Cand. Sci. Dissertation, St. Petersburg State Railway University, St. Petersburg, 1994 [in Russian].
Borodai, F.Ya. and Evdokimova, T.M., Heat-Resistant Composite Materials Based on Aluminophosphate Binders, Neorg. Mater., 1969, vol. 5, no. 8, pp. 1406–1410.
Belyankin, D.S., Toropov, N.A., and Konovalova, N.A., On the Action of Phosphoric Acid on Silica Glass, Trudy Leningr. Tekhnol. Inst. im. Lensoveta, 1951, no. 20, pp. 45–49.
Van Wazer, J.R., Phosphorus and Its Compounds, New York: Interscience, 1958. Translated under the title Fosfor i ego soedineniya, Moscow: Inostrannaya Literatura, 1962.
Rozovskii, A.Ya., Geterogennye khimicheskie reaktsii. Kinetika i makrokinetika (Heterogeneous Chemical Reactions: Kinetics and Macrokinetics), Moscow: Nauka, 1980 [in Russian].
Eksperimental’nye metody khimicheskoi kinetiki (Experimental Techniques of Chemical Kinetics), Emanuel’, N.N. and Kuz’min, N.G., Eds., Moscow: Moscow State University, 1985 [in Russian]
Rashkovan, I.L., Kuz’minskaya, L.N., and Kopeikin, V.A., On the Problem of Thermal Transformations of Aluminophosphate Binders, Neorg. Mater., 1966, vol. 2, no. 3, pp. 541–549.
Perepelitsyn, V.A., Osnovy tekhnicheskoi mineralogii i petrografii (Fundamentals of Technical Mineralogy and Petrography), Moscow: Nedra, 1987 [in Russian].
Polak, A.F., Tverdenie monomineral’nykh vyazhushchikh veshchestv (Curing of Monomineral Binding Agents), Moscow: Stroiizdat, 1966 [in Russian].
Author information
Authors and Affiliations
Additional information
Original Russian Text © A.I. Domanskii, Yu.I. Orlov, P.F. Rumyantsev, O.V. Shidlovskaya, 2007, published in Fizika i Khimiya Stekla.
Rights and permissions
About this article
Cite this article
Domanskii, A.I., Orlov, Y.I., Rumyantsev, P.F. et al. Kinetic regularities of the interaction of aluminum oxide and silicon dioxide single crystals with phosphoric acid. Glass Phys Chem 33, 55–61 (2007). https://doi.org/10.1134/S1087659607010087
Received:
Issue Date:
DOI: https://doi.org/10.1134/S1087659607010087