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Investigation into the influence of organic modifiers and ultradispersed hybrid fillers on the structure and properties of glass-ceramic coatings prepared by the sol-gel method

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Abstract

Glass-ceramic coatings on nickel and its alloys are produced from organic-inorganic hybrids by the sol-gel method. The coatings are applied using sol-gel systems composed of tetraethoxysilane (inorganic dopant), as well as of finely dispersed oxide and ultradispersed hybrid fillers. Acrylic and methacrylic acid derivatives are taken as organic modifiers. Oligocarbonate dimethacrylate-substituted tetranuclear titanium oxide clusters are used as the ultradispersed hybrid filler. The influence of the organic modifiers and ultradispersed hybrid fillers on the physicochemical processes occurring in the sol-gel systems and on the electrical parameters of the coatings are experimentally studied, and the data obtained are analyzed.

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Authors and Affiliations

  1. Grebenschikov Institute of Silicate Chemistry, Russian Academy of Sciences, ul. Odoevskogo 24/2, St. Petersburg, 199155, Russia

    E. V. Tarasyuk & O. A. Shilova

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    A. M. Bochkin & A. D. Pomogailo

Authors
  1. E. V. Tarasyuk
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  2. O. A. Shilova
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  3. A. M. Bochkin
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  4. A. D. Pomogailo
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Original Russian Text © E.V. Tarasyuk, O.A. Shilova, A.M. Bochkin, A.D. Pomogailo, 2006, published in Fizika i Khimiya Stekla.

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Tarasyuk, E.V., Shilova, O.A., Bochkin, A.M. et al. Investigation into the influence of organic modifiers and ultradispersed hybrid fillers on the structure and properties of glass-ceramic coatings prepared by the sol-gel method. Glass Phys Chem 32, 439–447 (2006). https://doi.org/10.1134/S1087659606040080

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  • DOI: https://doi.org/10.1134/S1087659606040080

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