Skip to main content
Log in

Effect of ZrO2 nanocrystals on the stabilization of the amorphous state of alumina and silica in the ZrO2-Al2O3 and ZrO2-SiO2 systems

  • Published:
Glass Physics and Chemistry Aims and scope Submit manuscript

Abstract

Structural and chemical transformations in the ZrO2-Al2O3 and ZrO2-SiO2 systems containing ZrO2 nanocrystals are examined. It is shown that the presence of zirconia nanoparticles in the oxide mixture retards the processes of crystallization and phase formation. The revealed effect is explained by the space blocking of nucleation in the systems under consideration.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Tret’yakov, Yu.D., Tverdofaznye reaktsii (Solid-Phase Reactions), Moscow: Khimiya, 1978.

    Google Scholar 

  2. Boldyrev, V.V., Control of Chemical Reactions in the Solid Phase, Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk, 1977, no. 3, pp. 48–58.

  3. Trisvetov, A.A., Ishutina, Zh.N., Gusarov, V.V., Malkov, A.A., and Malygin, A.A., Combined Effect of the Components on Solid-Phase Chemical Reactions in the System Al2O3-SiO2-TiO2, Zh. Obshch. Khim., 1997, vol. 67, no. 11, pp. 1795–1798 [Russ. J. Gen. Chem. (Engl. transl.), 1997, vol. 67, no. 11, pp. 1689–1692].

    Google Scholar 

  4. Gusarov, V.V., Malkov, A.A., Malygin, A.A., and Suvorov, S.A., Clusters of Aluminum Titanate in Compositions with a High Level of the Spatial and Structural Matching of the Components, Zh. Obshch. Khim., 1994, vol. 64, no. 4, pp. 554–557.

    CAS  Google Scholar 

  5. Smirnova, Zh.N., Gusarov, V.V., Malkov, A.A., Firsanova, T.V., Malygin, A.A., and Suvorov, S.A., High-Rate Synthesis of Mullite, Zh. Obshch. Khim., 1995, vol. 65, no. 2, pp. 199–204.

    CAS  Google Scholar 

  6. Smirnova, Zh.N., Gusarov, V.V., Malkov, A.A., Malygin, A.A., and Suvorov, S.S., Stabilization of the γ Form of Aluminum Oxide in the AlO1.5-SiO2 System with a Different Level of the Spatial and Structural Matching of the Components, Zh. Prikl. Khim. (St. Petersburg), 1995, vol. 68, no. 12, pp. 1950–1954.

    CAS  Google Scholar 

  7. Gusarov, V.V., Ishutina, Zh.N., Malkov, A.A., and Malygin, A.A., Peculiarities of the Solid-Phase Chemical Reaction in Formation of Mullite in the Nanosized Film Composition, Dokl. Akad. Nauk, 1997, vol. 357, no. 2, pp. 203–205 [Dokl. Chem. (Engl. transl.), 1997, vol. 357, no. 2, pp. 203–205].

    CAS  Google Scholar 

  8. Gusarov, V.V., Fast Solid-Phase Chemical Reactions, Zh. Obshch. Khim., 1997, vol. 67, no. 12, pp. 1959–1964 [Russ. J. Gen. Chem. (Engl. transl.), 1997, vol. 67, no. 12, pp. 1846–1851].

    Google Scholar 

  9. Pozhidaeva, O.V., Korytkova, E.N., Drozodva, I.A., and Gusarov, V.V., Phase State and Particle Size of Ultradispersed Zirconium Dioxide as Influenced by Conditions of Hydrothermal Synthesis, Zh. Obshch. Khim., 1999, vol. 69, no. 8, pp. 1265–1269 [Russ. J. Gen. Chem. (Engl. transl.), 1999, vol. 69, no. 8, pp. 1219–1222].

    Google Scholar 

  10. Diagrammy sostoyaniya sistem tugoplavkikh oksidov. Spravochnik. Vypusk 5. Dvoinye sistemy. Chast’ 1 (A Handbook on Phase Diagrams for Systems of High-Melting Oxides: Binary Systems), Galakhov, F.Ya., Ed., Leningrad: Nauka, 1985, issue 5, part 1, pp. 310–311.

    Google Scholar 

  11. Al’myasheva, O.V., Korytkova, E.N., Maslov, A.V., and Gusarov, V.V., Preparation of Nanocrystalline Alumina under Hydrothermal Conditions, Neorg. Mater., 2005, vol. 41, no. 5, pp. 540–547 [Inorg. Mater. (Engl. transl.), 2005, vol. 41, no. 5, pp. 460–467].

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Original Russian Text © O.V. Almjasheva, V.V. Gusarov, 2006, published in Fizika i Khimiya Stekla.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Almjasheva, O.V., Gusarov, V.V. Effect of ZrO2 nanocrystals on the stabilization of the amorphous state of alumina and silica in the ZrO2-Al2O3 and ZrO2-SiO2 systems. Glass Phys Chem 32, 162–166 (2006). https://doi.org/10.1134/S1087659606020064

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1087659606020064

Keywords

Navigation