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Genesis of Barite–Galena Ores at the Ushkatyn-III Deposit, Central Kazakhstan: Analysis of Geological, Mineralogical, and Isotopic (δ34S, δ13C, δ18O) Data

Abstract—

The Ushkatyn-III deposit is located in Central Kazakhstan, 300 km west of the city of Karaganda. The ore member consists of Upper Devonian carbonate rocks containing stratiform layers of hydrothermal–sedimentary iron–manganese and hydrothermal barite–lead ores. The study objects include barite–lead (barite–galena) ores localized within a reef limestone member. The major ore minerals are calcite, barite, and galena; characteristic minor minerals include quartz, hematite, sphalerite, pyrite, muscovite–phengite, chamosite, K-feldspar, albite, fluorite, dolomite, rhodochrosite, and siderite; and accessory minerals include native silver, rutile, ilmenite, chalcocite, acanthite, chalcopyrite, pyrargyrite, tetrahedrite, zircon, pyrophyllite, and apatite. Cerussite, pyromorphite, kaolinite, montmorillonite, and malachite are identified as supergene minerals. Cerussite is one of the main minerals in the oxidation zone. Three major ore varieties are distinguished in terms of texture. They are related by layered–banded, pocketlike–net, and massive spotted mutual transitions. The ore structure is indicative of the fact that barite and galena were mostly deposited in open pores and fractures of incompletely lithified carbonate deposits. Based on δ34Sbarite = 10.9–15.3‰, the barite formation involved isotopically heavy sulfur of the sulfate ion dissolved in seawater, whereas the δ34Ssulfides (galena) values from –25.7 to –12.6‰ record 32S-enriched (light isotope) hydrogen sulfide generated in the course of bacterial sulfate reduction. A formation model is proposed for the Ushkatyn-III deposit. According to this model, its barite–galena, iron, and manganese ores were products of a single hydrothermal system that developed within a thick sedimentary sequence. Barite–galena ores formed near the seabed surface with the discharge of hydrothermal solutions in internal zones of the still-forming reef. The ore material was deposited in the area where the hydrothermal solutions carrying Ba, Pb, Zn, Fe, Mn, and other elements were mixed with near-surface waters filling pores and fractures inside the reef, characterized by bacterial reduction of seawater sulfate ion to hydrogen sulfide. Penetrating through the reef, the fluids lost most of the Ba and Pb, deposited as barite and galena, but retained Zn, Fe, and Mn in dissolved form. Subsequently, Fe and Mn were deposited as oxides: Fe, on the reef surface or at some distance from it, and Mn, at a considerable distance. Zn dispersed in the surrounding space without forming any orebodies.

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ACKNOWLEDGMENTS

We are grateful to A.Yu. Burkovskii, Chairman of the Board of the Zhairem Mining and Processing Plant (Zhairem, Republic of Kazakhstan), and geologists of this enterprise: V.A. Volkov, O.A. Muratov, A.N. Abdelmanova, Zh.Zh. Akimeev, K.A. Akshalova, A.S. Burkhanov, R.B. Ivakova, and G.K. Turlynova for assistance in field research. The studies were carried out using the analytical capabilities of the Center of X-ray Diffraction Studies and Microscopy and Microanalysis Center, St. Petersburg State University (St. Petersburg), and the Oregenesis Mineralogy Laboratory, Institute of Mineralogy, Southern Ural Federal Scientific Center of Mineralogy and Geoecology, Ural Branch, Russian Academy of Sciences (Miass).

Funding

The study was carried out under the state task of the Institute of Mineralogy, Southern Ural Federal Scientific Center of Mineralogy and Geoecology, Ural Branch, Russian Academy of Sciences, “Mineralogical and Geochemical Evolution and Metallogeny of Hydrothermal, Authigenic, and Supergene Ore-Forming Systems” (topic no. АААА-А19-119061790049-3).

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Brusnitsyn, A.I., Sadykov, S.A., Perova, E.N. et al. Genesis of Barite–Galena Ores at the Ushkatyn-III Deposit, Central Kazakhstan: Analysis of Geological, Mineralogical, and Isotopic (δ34S, δ13C, δ18O) Data. Geol. Ore Deposits 64, 78–103 (2022). https://doi.org/10.1134/S1075701522030023

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Keywords:

  • barite and lead deposits
  • hydrothermal process
  • and Central Kazakhstan