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Composition of Fluids Responsible for Gold Mineralization in the Pechenga Structure of the Pechenga–Imandra–Varzuga Greenstone Belt, Kola Peninsula, Russia

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Abstract

This study presents the first fluid inclusion data from quartz of albite–carbonate–quartz altered rocks and metasomatic quartzite hosting gold mineralization in the Pechenga structure of the Pechenga–Imandra–Varzuga greenstone belt. A temperature of 275–370°C, pressure of 1.2–4.5 kbar, and the fluid composition of gold-bearing fluid are estimated by microthermometry, Raman spectroscopy, and LA-ICP-MS of individual fluid inclusions, as well as by bulk chemical analyses of fluid inclusions. In particular, the Au and Ag concentrations have been determined in fluid inclusions. It is shown that albite–carbonate–quartz altered rocks and metasomatic quartzite interacted with fluids of similar chemical composition but under different physicochemical conditions. It is concluded that the gold-bearing fluid in the Pechenga structure is similar to that of orogenic gold deposits.

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References

  • Akhmedov, A.M., Voronyaeva, L.V., Pavlov, V.A., et al., Gold potential of the South Pechenga structural zone (Kola Peninsula): types of occurrences and prospects for discovery of economic gold contents, Regional. Geol. Metallogen., 2004, no. 20, pp. 139–151.

    Google Scholar 

  • Allan, M.M., Yardley, B.W.D., Forbes, L.J., et al., Validation of LA-ICP-MS fluid inclusion analysis with synthetic fluid inclusions, Am. Mineral., 2005, vol. 90, pp. 1767–1775.

    Article  Google Scholar 

  • Balagansky, V.V. and Belyaev, O.A., Gold-bearing shear zones in the Early Precambrian of the Kola Peninsula: forecasting and first results, Petrografiya XXI veka. T. 3. Petrologiya i rudonosnost' regionov SNG i Baltiiskogo shchita (Petrography of the 21st Century. Volume 3. Petrology and Ore Potential of the Regions of CIS and the Baltic Shield), Apatity: KNTs RAN, 2005, pp. 37–38.

    Google Scholar 

  • Balashov, Yu.A., Geochronology of the Paleoproterozoic rocks of the Pechenga–Varzuga structure of the Kola Peninsula, Petrologiya, 1996, vol. 4, no. 1, pp. 3–25.

    Google Scholar 

  • Bodnar, R.J. and Vityk, M.O., Interpretation of microterhmometric data for H2O-NaCl fluid inclusions, Fluid Inclusions in Minerals: Methods and Applications, Benedetto De Vivo & Maria Luce Frezzotti, Pontignano: Siena, 1994, pp. 117–130.

    Google Scholar 

  • Bodnar, R.J., Lecumberri-Sanchez, P., Moncada, D., and Steele-Maclnnes, P., Fluid inclusions in hydrothermal ore deposits, Reference Module in Earth Systems and Environmental Sciences. Treatise on Geochemistry, 2nd Edition, Elsevier, 2014, pp. 119–142.

    Google Scholar 

  • Borisenko, A.S., Cryometric study of salt composition of the gas–liquid inclusions in minerals, Geol. Geofiz., 1977, no. 8, pp. 16–27.

    Google Scholar 

  • Brown, P., Flincor: a computer program for the reduction and investigation of fluid inclusion data, Am. Mineral., 1989, vol. 74, pp. 1390–1393.

    Google Scholar 

  • Collins, P.L.P., Gas hydrates in CO2-bearing fluid inclusions and the use of freezing data for estimation of salinity, Econ. Geol., 1979, vol. 74, pp. 1435–1444.

    Article  Google Scholar 

  • Duk, G.G., Strukturnaya–metamorficheskaya evolyutsiya porod Pechengskogo kompleksa (Structural–Metamorphic Evolution of the Rocks of the Pechenga Complex) Moscow-Leningrad: Nauka, 1977.

    Google Scholar 

  • Faure, G., Principles of Isotope Geology, New York; Wiley, 1986.

    Google Scholar 

  • Garofalo, P.S., Fricker, M.B., Gunther, D., et al., Physical-chemical properties and metal budget of Au-transporting hydrothermal fluids in orogenic deposits, Geol. Soc. London: Spec. Publ., 2014, vol. 402, pp. 71–102.

    Article  Google Scholar 

  • Groves, D.I., Goldfarb, R.J., Gebre-Mariam, M., and Robert, F., Orogenic gold deposits: a proposed classification in the context of their crustal distribution and relationship to other gold deposit types, Ore Geol. Rev., 1998, vol. 13, pp. 7–27.

    Article  Google Scholar 

  • Guillong, M., Meier, D.L., Allan, M.M., et al., Appendix A6: SILLS: a Matlab-based program for the reductions of laser ablation ICP-MS data of homogenous materials and inclusions, Laser Ablation ICP-MS in the Earth Sciences: Current Practices and Outstanding Issues, Mineral. Ass. Canada, 2008, vol. 40, pp. 328–333.

    Google Scholar 

  • Ivashchenko, V.I. and Golubev, A.I., Zoloto i platina Karelii: formatsionno-geneticheskie tipy orudeneniya i perspektivy (Gold and Platinum: Formation-Genetic Types of Mineralization and Prospects), Petrozavodsk: IG Kar. NTs RAN, 2011.

    Google Scholar 

  • Kalinin, A.A., Bayanova T.B., Lyalina, L.M., et al., Gold occurrences of the Southern Pechenga structural zone: new isotope-geochemical data, Geologiya i geokhronologiya porodoobrazuyushchikh i rudnykh protsessov v kristallicheskikh shchitakh: Mater. Vserossiiskoi (s mezhdunarodnym uchastiem) konf., Apatity, 2013 (Geology and Geochronology of the Rock-Forming and Ore Processes in the Crystalline Shields. Proceedings of All-Russian Conference with International Participance), Apatity, 2013, pp. 69–71.

    Google Scholar 

  • Kazitsyn, Yu.V and Rudnik, V.A., Rukovodstvo k raschetu balansa veshchestva i vnutrennei energii pri formirovanii metasomaticheskikh porod (A Handbook to Calculation of Mass Balance and Internal Energy during Formation of Metasomatic Rocks), Moscow: Nedra, 1968.

    Google Scholar 

  • Kryazhev, S.G., Prokof’ev, V.Yu., and Vasyuta, Yu.V., Application of ICP MS mehod in analyzing composition of ore-forming fluids, Vestn. Mosk. Gos. Univ., Ser. 4 Geol., 2006, no. 4, pp. 30–36.

    Google Scholar 

  • Melezhik, V.A. and Sturt, B.A., General geology and evolutionary of the Early Proterozoic Polmak–Pasvik–Pechenga–Imandra/Varzuga–Ust’ponoy greenstone belt in the northeastern Baltic Shield, Earth Sci. Rev., 1994, vol. 36, pp. 205–241.

    Article  Google Scholar 

  • Mints, M.V., Glaznev, V.N., Konilov, A.N., et al., Rannii dokembrii severo-vostoka Baltiiskogo shchita: Paleogeodinamika, stroenie i evolyutsiya kontinental’noi kory (Early Precambrian of the Norheastern Baltic Shield: Paleogeodynamics, Structure, and Evolution of Continental Crust), Moscow: Nauchnyi mir, 1996.

    Google Scholar 

  • Naumov, V.B., Dorofeeva, V.A., and Mironova, O.F., Physicochemical formation parameters of hydrothermal mineral deposits: evidence from fluid inclusions. II. Gold, silver, lead, and zink deposits, Geochem. Int., 2014, vol. 52, no. 6, pp. 433–455.

    Article  Google Scholar 

  • Pokrovski, G.S., Akinfiev, N.N., Borisova, A.Y., et al., Gold speciation and transport in geological fluids: insights from experiments and physical-chemical modeling, Geol. Soc. London: Spec. Publ., 2014, vol. 402, pp. 9–70.

    Article  Google Scholar 

  • Prokofiev, V.Yu., Banks, D.A., Lobanov, K.V., et al., Aurich fluid inclusions in gold-bearing quartz from the Kola superdeep borehole (SG-3), Bull. Geol. Soc. Finland. Spec. Volume. Abstracts of the 32nd Nordic Geological Winter Meeting, 2016. Helsinki: Finland. Geological Society of Finland, 2016.

    Google Scholar 

  • Ridley, J.R. and Diamond, L.W., Fluid chemistry of orogenic lode gold deposits and implications for genetic models, Gold in 2000. SEG Reviews, 2000, vol. 13, pp. 141–162.

    Google Scholar 

  • Saunders, J.A. and Burke, M., Formation and aggregation of gold (Electrum) nanoparticles in epithermal ores, Minerals, 2017, vol. 7, no. 7, p. 163. https://doi.org/10.3390/min709016

    Article  Google Scholar 

  • Seismologicheskaya model' litosfery severnoi Evropy: Laplandsko-Pechengskii raion (Seismological Model of the Lithosphere of Northern Europe: Lapland–Pechenga Area), Sharov, N.V, Eds., Apatity: KNTs RAN, 1997.

  • Skuf’in, P.K., Bayanova, T.B., Mitrofanov, F.P., et al., The absolute age of granitoids from the Shuoniyavri Pluton in the southern framework of the Pechenga Structure, the Kola Peninsula, Dokl. Earth Sci., 2000, vol. 370, no. 1, pp.114–117.

    Google Scholar 

  • Skuf’in, P.K. and Theart, H.F.J., Geochemical and tectono-magmatic evolution of the volcano-sedimentary rocks of Pechenga and other greenstone fragments within the Kola greenstone belt, Russia, Precambrian Res., 2005, vol. 141, pp. 1–48.

    Article  Google Scholar 

  • Skuf’in, P.K., Elizarov, D.V., and Zhavkov, V.A., Geology and geochemistry of the volcanic rocks of the South Pechenga Lithotectonic Zone, Vestn. Murmansk. Gos. Tekhn. Univ., 2009, vol. 12, no. 3, pp. 416–435.

    Google Scholar 

  • Smol’kin, V.F., Mitrofanov, F.P., Avedisyan, A.A., et al., Magmatizm, sedimentogenez i geodinamika Pechengskoi paleoriftogennoi struktury (Magmatism, Sedimentogenesis, and Geodynamics of the Pechenga Paleorift Structure), Apatity: KNTs RAN, 1995.

    Google Scholar 

  • Sundblad, K., Metallogeny of gold in the Precambrian of Northern Europe, Econ. Geol., 2003, vol. 98, pp. 1271–1290.

    Article  Google Scholar 

  • Vetrin, V.R., Petrology of Granitoids in the southern framing of Pechenga (Kola Peninsula), Izv. Akad. Nauk SSSR, Ser. Geol., 1988, no. 6, pp. 20–33.

    Google Scholar 

  • Voronyaeva, L.V., Geology and Gold Potential of the South Pechenga Structural Zone, Extended Abstract of Candidate’s (Geol.-Min.) Dissertation, St. Petersburg: VSEGEI, 2008.

    Google Scholar 

  • Zharikov, V.A., Rusinov, V.L., Marakushev, A.A., et al., Metasomatizm i metasomaticheskie porody (Metasomatism and Metasomatic Rocks), Moscow: Nauchnyi mir, 1998.

    Google Scholar 

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Correspondence to V. Yu. Prokofiev.

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Original Russian Text © V.Yu. Prokofiev, A.A. Kalinin, K.V. Lobanov, D.A. Banks, A.A. Borovikov, M.V. Chicherov, 2018, published in Geologiya Rudnykh Mestorozhdenii, 2018, Vol. 60, No. 4, pp. 317–341.

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Prokofiev, V.Y., Kalinin, A.A., Lobanov, K.V. et al. Composition of Fluids Responsible for Gold Mineralization in the Pechenga Structure of the Pechenga–Imandra–Varzuga Greenstone Belt, Kola Peninsula, Russia. Geol. Ore Deposits 60, 277–299 (2018). https://doi.org/10.1134/S1075701518040037

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