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Composition and chemical microprobe dating of U-Th-bearing minerals. Part I. Monazites from the Urals and Siberia

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Abstract

To develop chemical microprobe timing of U-Th-bearing minerals, monazite grains from several localities in the Ural and Siberia have been dated using upgraded measurement techniques and age calculation based on original software. The samples were taken from pegmatites of the Ilmeny Mountains and the Ilmeny-Vishnevy Mountains Complex in the South Urals; pegmatites from the Adui granitic pluton and its framework in the Central Urals; gneisses and granulites of the Taratash Complex in the South Urals; and felsic gneisses from the Transangara region of the Yenisei Ridge. Scrutiny of the composition, heterogeneity, and chemical substitution of U and Th ions is a necessary stage of chemical dating aimed at estimating the degree of closeness of the U-Th-Pb system and unbiased screening of analytical data. The results obtained have been compared with the known isotopic ages of the studied minerals; the compared data are satisfactorily consistent.

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References

  • Boatner L.A. Synthesis, Structure, and Properties of Monazite, Pretulite, and Xenotime, Rev. Mineral. Geochem., 2002. vol. 48. pp. 87–121.

    Article  Google Scholar 

  • Cocherie, A., Legendre, O., Peucat, L.L., and Kouamelan, A.N., Geochronology of Polygenetic Monazites Constrained by in Situ Electron Microprobe Th-U-Total Lead Determination: Implications for Lead Behavior in Monazite, Geochim. Cosmochim. Acta, 1998, vol. 62, pp. 2475–2497.

    Article  Google Scholar 

  • Cocherie, A. and Albarede, F., An Improved U-Th-Pb Age Calculation for Electron Microprobe Dating of Monazite, Geochim. Cosmochim. Acta, 2001, vol. 65, no. 24, pp. 4509–4522.

    Article  Google Scholar 

  • Copeland, P., Parrish, R.R., and Harrison, T.M., Identification of Inherited Radiogenic Pb in Monazite and Its Implication for U-Pb Systematics, Nature, 1988, vol. 333, pp. 760–763.

    Article  Google Scholar 

  • Cressey, G., Wall, F., and Cressey, B.A., Differential REE Uptake by Sector Growth of Monazite, Min. Mag., 1999, vol. 63, pp. 813–828.

    Article  Google Scholar 

  • Dahl, P.S., Hamilton, M.A., Jercinovic, M.J., Terry, M.P., Williams, M.L., and Frey, R., Comparative Isotopic and Chemical Geochronometry of Monazite, with Implications for U-Th-Pb Dating by Electron Microprobe: An Example from Metamorphic Rocks of the Eastern Wyoming Craton (USA), Am. Mineral., 2005, vol. 90, pp. 619–638.

    Article  Google Scholar 

  • Ewing R.C., Meldrum A., Wang L., Weber W.J., and Corrales L.R. Radiation Effects in Zircon, Rev. Mineral. Geochem., 2003, vol. 53, pp. 387–425.

    Article  Google Scholar 

  • Fershtater, G.B., Gerdes, A., and Smirnov, V.N., Age and Formation History of the Adui Granitic pluton, in Ezhegodnik-2002 (Yearbook-2002), Yekaterinburg: Inst. Geol. Geochem., 2003, pp. 146–150.

    Google Scholar 

  • Huminicki D.M.C. and Hawthorne F.C. The Crystal Chemistry of the Phosphate Minerals, Rev. Mineral. Geochem., 2002, vol. 48. pp. 123–253.

    Article  Google Scholar 

  • Jercinovic, M.J. and Williams, M.L., Analytical Perils (and Progress) in Electron Microprobe Trace Element Analysis Applied to Geochronology: Background Acquisition, Interferences, and Beam Irradiation Effects, Am. Mineral., 2005, vol. 90, pp. 526–546.

    Article  Google Scholar 

  • Khiller, V.V., Composition, Crystal Chemistry, and Evolution of the U-Th-Pb System of Minerals Chronometers from Experimental Study and Computer Simulation, Cand. Sci. (Geol.-Mineral.) Dissertation, Yekaterinburg: Inst. Geol. Geochem., 2010.

    Google Scholar 

  • Konilov, A.N., Romanenko, I.M., Filippov, M.N., and Petrov, D.B., Capability of Geochronology of Monazites with Th-U-Pb Method from the Data of X-ray Spectral Analysis, in Tezisy dokladov Vseross. konferentsii Analitika Rossii-2004 (Abstracts of the All-Russia Conference on Analytics in Russia-2004), Moscow, 2004, pp. 265–266.

  • Krasnobaev, A.A., Tsirkon kak indikator geologicheskikh protsessov (Zircon As an Indicator of Geological Processes), Moscow: Nauka, 1986.

    Google Scholar 

  • Krasnobaev, A.A., Fershtater, G.B., Bea, F., and Montero, P., Polygenetic Zircons in the Adui Pluton, the Central Urals, Doklady Earth Sci., 2006, vol. 409A, no. 7, pp. 1096–1100.

    Article  Google Scholar 

  • Lennykh, V.I., Metamorphic Complexes of the Western Slope of the Urals, in Pre-Ordovician istoriya Urala (Pre-Ordovician History of the Urals), Sverdlovsk: Ural Sci. Center, USSR Acad. Sci., 1980, pp. 3–40.

    Google Scholar 

  • Likhanov, I.I., Kozlov, P.S., Polyansky, O.P., Popov, N.V., Reverdatto, V.V., Travin, A.V., and Vershinin, A.E., Neoproterozoic Age of Collisional Metamorphism in the Transangara Region of the Yenisei Ridge (Based on 40Ar/39Ar Data), Doklady Earth Sci., 2007, vol. 413, no. 2, pp. 234–237.

    Article  Google Scholar 

  • Ludwig, K.R., User’s Manual for ISOPLOT/EX, Version 2. A Geochronological Toolkit for Microsoft Excel, Berkeley: Geochronology Center, Spec. Publ. no. 1a, 1999.

    Google Scholar 

  • Montel, J.-M., Foret, S., Veschambre, M., Nicollet, Ch., and Provost, A., Electron Microprobe Dating of Monazite, Chem. Geol., 1996, vol. 131, pp. 37–53.

    Article  Google Scholar 

  • Montel, J.-M., Devidal, J.L., and Avignant, D., X-Ray Diffraction Study of Brabantite-Monazite Solid Solutions, Chem. Geol., 2002, vol. 191, p. 89.

    Article  Google Scholar 

  • Mullica, D.F., Milligan, W.O., Grossie, D.A., and Beall, G.W., Ninefold Coordination in LaPO4: Pentagonal Interpenetrating Tetrahedral Polyhedron, Inorg. Chim. Acta, 1984, vol. 95, pp. 231–236.

    Article  Google Scholar 

  • Ni, Y., Hughes, J.M., and Mariano, A.N., Crystal Chemistry of the Monazite and Xenotime Structures, Am. Mineral., vol. 80, pp. 21–26.

  • Petrov, D.B., X-Ray Spectral Determination of Thorium, Uranium, and Lead, Cand. Sci. (Techn) Dissertation, Moscow: GTU MISI, 2007.

    Google Scholar 

  • Popov, V.A. and Popova, V.I., Mineralogy of Pegmatites in the Ilmen Mountains, Mineralogicheskii al’manakh (Mineralogical Almanac), Moscow: Ekost, 2006, issue 9.

    Google Scholar 

  • Popova, V.I. and Churin, E.I., Zoning and Sectoriality of Monazite-(Ce) from Granite Pegmatites of the Central and South Urals, Geol. Ore Deposits, 2010, vol. 52, spec. issue 7 (Zapiski Russian Mineral. Soc.), pp. 646–655.

    Article  Google Scholar 

  • Popova, V.I., Khiller, V.V., Erokhin, Yu.V., and Popov, V.A., Monazites of the Late Granitic Pegmatites in the Ilmen Mountains: Chemical Dating of Zonal-Sectorial Crystals, in Novye dannye o mineralakh (New Data on Minerals), Moscow, 2010, issue 45, pp. 72–78.

  • Rhede, D., Wendt, I., and Forster, H.J., A Three-Dimensional Method for Calculating Independent Chemical U/Pb-and Th/Pb Ages of Accessory Minerals, Chem. Geol, 1996, vol. 30, pp. 247–253.

    Article  Google Scholar 

  • Romanenko, I.M., Mukhanova, A.A., Petrov, D.B, and Konilov, A.N., Technique of Dating of Minerals, Rocks, and Ores with X-Ray Spectral Microanalysis, in Materialy VI Vserossiiskoi konferentsii po rentgenospektral’nomu analizu (Proceedings of the 6th All-Russia Conference on X-Ray Spectral Analysis), Krasnodar: Krasnodar State Univ., 2008, p. 175.

    Google Scholar 

  • Savko, K.A., Samsonov, A.V., Pilyugin, S.M., Sal’nikova, E.B., and Artemenko, G.V., New data on the Age of Granulite Metamorphism in the Kursk-Besedino Block of the Voronezh Crystalline Massif, Vestnik, Vestn.VGU, Seriya Geologiya, 2009, no. 1, pp. 84–93.

  • Seydoux-Guillaume, A.M., Paquette, J.L., Wiedenbeck, M., Montel, J.M., and Heinrich, W., Experimental Resetting of the U-Th-Pb Systems in Monazite, Chem. Geol., 2002, vol. 165–181.

  • Smirnov, V.N., Ivanov, K.S., Krasnobaev, A.A., Bushlyakov, I.N., and Kaleganov, B.A., Results of K-Ar Dating of the Adui Granitic Pluton, the Eastern Slope of the Central Urals, Litosfera, 2006, no. 2, pp. 148–156.

  • Spear, F.S. and Pyle, J.M., Apatite, Monazite, and Xenotime in Metamorphic Rocks, Rev. Mineral. Geochem, 2002, vol. 48, pp. 293–335.

    Article  Google Scholar 

  • Suzuki, K., Adachi, M., and Tanaka, T., 1991. Middle Precambrian Provenance of Jurassic Sandstone in the Mino Terrane, Central Japan: Th-U-Total Pb Evidence from an Electron Microprobe Monazite Study, Sedim. Geol., 1991, vol. 75, pp. 141–147.

    Article  Google Scholar 

  • Suzuki, K., Adachi, M., and Kajizuka, I., Electron Microprobe Observations of Pb Diffusion in Metamorphosed Detrital Monazite, Earth Planet. Sci. Lett., 1994, vol. 128, pp. 391–405.

    Article  Google Scholar 

  • Suzuki, K. and Kato, T., CHIME Dating of Monazite, Xenotime, Zircon and Polycrase: Protocol, Pitfalls and Chemical Criterion of Possibly Discordant Age Data, Gondwana Res., 2008, vol. 14, pp. 569–586.

    Article  Google Scholar 

  • Vernikovsky, V.A., Vernikovskaya, A.E., Wingate, M.T.D., Popov, N.V., and Kovach, V.P., The 880-864 Ma Granites of the Yenisey Ridge, Western Siberian Margin: Geochemistry, SHRIMP Geochronology, and Tectonic Implications, Precambr. Res., 2007, vol. 154, pp. 175–191.

    Article  Google Scholar 

  • Votyakov, S.L., Khiller, V.V., Shchapova, Yu.V., and Porotnikov, A.V., Chemical Electron Microprobe Dating of Mineral Concentrators of Radioactive Elements: Methodical Aspects, Litosfera, 2010, no. 4, pp. 94–115.

  • Votyakov, S.L., Khiller, V.V., Shchapova, Yu.V., and Porotnikov, A.V., Simulation of the Time Evolution of the U-Th-Pb System: The Basis for Chemical Microprobe Dating of Minerals Accumulating Uranium and Thorium, Doklady Earth.Sci., 2011, vol. 437, no. 2, pp. 469–472.

    Article  Google Scholar 

  • Williams, M.L., Jercinovic, M.J., and Hetherington, C.J., Microprobe Monazite Geochronology: Understanding Geologic Processes by Integrating Composition and Chronology, Ann. Rev. Earth Planet. Sci., 2007, vol. 35, pp. 137–175.

    Article  Google Scholar 

  • York, D., Least-Squares Fitting of a Straight Line, Can. J. Phys., 1966, vol. 44, pp. 1079–1086.

    Article  Google Scholar 

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Correspondence to S. L. Votyakov.

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Original Russian Text © S.L. Votyakov, V.V. Khiller, Yu.V. Shchapova, 2012, published in Zapiski Rossiiskogo Mineralogicheskogo Obshchestva, 2012, No. 1, pp. 45–60.

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Votyakov, S.L., Khiller, V.V. & Shchapova, Y.V. Composition and chemical microprobe dating of U-Th-bearing minerals. Part I. Monazites from the Urals and Siberia. Geol. Ore Deposits 54, 625–637 (2012). https://doi.org/10.1134/S1075701512080119

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