Abstract
The phosphate and sulfate-phosphate minerals in the sillimanite-bearing rocks of the Kyakhta deposit are considered. The mineral assemblages of the high-Al rocks were formed during prograde and retrograde stages of metamorphism. The first stage is characterized by the formation of sillimanite, corundum, muscovite, quartz, rutile, titanohematite, magnetite, feldspar, biotite, lazulite, and wagnerite. The muscovite composition showed that sillimanite paragenesis was formed at temperatures above 510–600°C. According to oxygen isotope thermometry, the minimum metamorphic temperature for quartz and titanohematite is 690°C. Andalusite, diaspore, quartz, pyrophyllite, muscovite, and a wide range of phosphates and sulfate-phosphates crystallized during the retrograde stage. The decrease in temperature and increase in the water content led to the following sequence of mineral formation: Mg-Fe-Al-Ca-REE-rich phosphates (lazulite, scorzalite, augelite, apatite, and monazite) → Ca-Sr sulfate-phosphates (woodhouseite and svanbergite) → sulfate (barite) → Sr-Ca-Ba aluminophosphates (goyazite, crandallite, and gorceixite). The chemical compositions of phosphates and sulfate-phosphates minerals and their formation conditions are discussed.
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References
H. G. Dill, “The Geology of Aluminium Phosphates and Sulfates of the Alunite Supergoup,” Earth-Sci. Rev. 53, 35–93 (2001).
H. P. Eugster and H. S. Yoder, “A Join Muscovite-Paragonite,” Carnegie Inst. Geophys. Lab. Yearbook 55, 75 (1955).
I. A. Izbrodin, Candidate’s Dissertation in Geology and Mineralogy (Ulan-Ude, 2006).
I. A. Izbrodin, G. S. Ripp, and N. S. Karmanov, “Sulfate-Bearing Apatite of the Kyakhta Sillimanite Deposit (Western Baikal Region),” Zap. Ross. Mineral. O-va 135(2), 71–82 (2006).
J. L. Jambor, “Nomenclature of the Alunite and the Jarosites,” Canad. Miner. 37 1323–1341 (1999).
S. V. Kanakin, N. S. Karmanov, and M. N. Lapina, “Algorithm of Background Calculation in X-Ray Spectral Microanalysis with Wave Dispersion,” in Proceedings of III All-Russia and VI Siberian Conference on the X-Ray Analysis (Irkutsk, 1998), p. 66.
N. S. Karmanov, S. V. Kanakin, and G. S. Ripp, “Study of REE and EPG Minerals with EPMA in Presence of Spectral Superposition,” in Proceedings of All-Russia Scientific Conference on Geology, Geochemistry, and Geophysics on the Turn of XX and XXI Centuries (Russ. Found. Basic Res.-Sib. Branch Russ. Acad. Sci., Irkutsk, 2002), pp. 261–262.
V. V. Khlestov, Candidate’s Dissertation in Geology and Mineralogy (Novosibirsk, 1964), pp. 16–18.
V. V. Khlestov and E. N. Ushakova, “Petrography and Genesis of the Kyakhta Sillimanite Deposit of Buryat ASSR,” in Theoretical and Experimental Mineralogy (Nauka, Novosibirsk, 1963), No. 1, pp. 197–239 [in Russian].
I. I. Lefevre and L. E. Patterson, “Hydrothermal Assemblages at Aluminian Serpentine Florencite and Kyanite in Zairian Copperbelt,” Ann. Soc. Geol. Belg. 105, 51–71 (1982).
R. P. Liferovich, V. N. Yakovenchuk, Ya. A. Pakhomovsky, and A. N. Bogdanova, “Goyazite from Dolomite Carbonatites of the Kovdor Massif,” Zap. Vseross. Mineral. O-va 126(5), 58–65 (1997).
V. A. Makrygina, I. L. Lapides, and B. V. Petrov, “Lazulite in Metamorphosed Rocks of the North Baikal Higland,” in Minerals and Mineral Assemblages of Rocks (Nauka, Leningrad, 1976), pp. 102–107 [in Russian].
R. N. Mil’kevich and N. V. Kotov, “Geology, Polymetamorphism, and Paleothermometry of Metamorphic Rock Complexes from the Unda-Shilka Interfluve (Eastern Baikal Region),” in Magmatism and Metamorphizm (Leningr. State Univ., Leningrad, 1972), Vol. IV, pp. 46–57 [in Russian].
L. E. Mordberg, “Geochemical Evolution of a Devonian Diaspore-Crandallite-Svanbergite-Bearing Weathering Profile in the Middle Timan, Russia,” J. Geoch. Explor. 66, 351–361 (1999).
G. Morteani and D. Ackermand, “Aluminium Phosphates in Muscovite-Kyanite Metaquartzites from Passo di Vizze (Alto Adige, NE Italy),” Eur. J. Mineral. 8, 853–869 (1996).
G. Morteani and D. Ackermand, “Mineralogy and Geochemistry of Al-phosphate and Al-Borosilicate-Bearing Metaquartzites of the Northern Serra do Espinhaco (State of Bahia, Brazil),” Miner. Petrol. 80, 59–81 (2004).
B. Rasmussen, “Early Diagenetic REE-Phosphate Minerals (Florencite, Gorceixite, Crandallite, and Xenotime) in Marine Sandstones; A Major Sink for Oceanic Phosphorus,” Am. J. Sci. 296, 601–632 (1996).
S. A. Repina and N. S. Yuzeeva, “REE and Strontium Al-Phosphate in Crystal-Bearing Veins at the Piramida Deposit, the Subpolar Urals,” Zap. Ross. Mineral. O-va 134(6), 103–110 (2005).
G. S. Ripp, S. V. Kanakin, and M. N. Shcherbakova, “Phosphate Mineralization in Metamorphosed High-Alumina Rocks at the Ichetui Occurrence (Southwestern Transbaikal Region),” Zap. Vseross. Mineral. O-va 127(6), 98–108 (1998).
Ek Roland and P. Nysten, “Phosphate Mineralogy of the Halsjoberg and Hokensas Kyanite Deposits,” Geol. Foren. Stokholm Forhadl., No. 1, 9–18 (1990).
P. Schmid-Beurmann, St. Knitter, and L. Cemic, “P-T Stability of the Lazulite-Scorzalite Solid Solution Series,” Miner. Petrol. 70, 55–71 (2000).
P. Schmid-Beurmann, G. Morteani, and L. Cemic, “Experimental Determination of the Upper Stability of Scorzalite, FeAl2[OH PO4]2, and the Occurrence of Minerals with a Composition Intermediate between Scorzalite and Lazulite(ss) up to Conditions of the Amphibolites Facies,” Miner. Petrol. 61, 211–222 (1997).
Z. D. Sharp, “Oxygen Isotope Geochemistry of the Al2SiO5 Polymorphs,” Am. J. Sci. 295, 1058–1076 (1995).
V. I. Silaev, V. N. Filippov, and M. Yu. Sokerin, “Solid Solutions in Woodhouseite-Svanbergite-Florencite in Secondary Quartzites,” Zap. Vseross. Mineral. O-va 130(1), 99–110 (2001).
M. Ya. Somina and A. G. Bulakh, “Florencite from Carbonatites of the Eastern Sayan and Some Issues of Chemical Constitution of the Cradallite Mineral Group,” Zap. Vsesoyuzn. Mineral. O-va 95(5), 537–550 (1966).
W S. Wise, “Solid Solution between the Alunite, Woodhousite, and Crandallite Mineral Series,” Neues Jb. Miner. Monatsh., No. 12, 540–545 (1975).
W. S. Wise and S. E. Loh, “Equilibria and Origin of Minerals in the System Al2O-AlPO4-H2O,” Am. Miner. 61, 409–413 (1976).
Y.-F. Zheng and K. Simon, “Oxygen Isotope Fractionation in Hematite and Magnetite: A Theoretical Calculation and Application to Geothermometry of Iron Formation,” Eur. J. Miner. 3, 877–886 (1991).
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Original Russian Text © I.A. Izbrodin, G.S. Ripp, N.S. Karmanov, 2009, published in Zapiski RMO (Proceedings of the Russian Mineralogical Society), 2009, Pt. CXXXVII, No. 3, pp. 94–106.
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Izbrodin, I.A., Ripp, G.S. & Karmanov, N.S. Phosphate and sulfate-phosphate mineralization in sillimanite-bearing rocks at the Kyakhta deposit, western Transbaikal region. Geol. Ore Deposits 51, 617–626 (2009). https://doi.org/10.1134/S1075701509070101
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DOI: https://doi.org/10.1134/S1075701509070101