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Reaction of Nitromethane with Phenylacetylene in Superbasic Medium

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Abstract

Nitromethane reacted with phenylacetylene in superbasic media [KOH (t-BuOK)/DMSO] to give E and Z isomers of 4-benzyl-3-styryl-4,5-dihydro-1,2-oxazole 2-oxide, 2-benzyl-3-hydroxypropanenitrile, and 1-benzyl-2-nitrocyclopropane.

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ACKNOWLEDGMENTS

This study was performed using the facilities of the Baikal joint analytical center, Siberian Branch, Russian Academy of Sciences.

Funding

This work was supported by ongoing institutional funding. No additional grants to carry out or direct this particular research were obtained.

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Authors and Affiliations

  1. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 664033, Irkutsk, Russia

    N. A. Lobanova, I. V. Tatarinova, I. A. Ushakov, E. Yu. Schmidt & B. A. Trofimov

Authors
  1. N. A. Lobanova
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  2. I. V. Tatarinova
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  3. I. A. Ushakov
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  4. E. Yu. Schmidt
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  5. B. A. Trofimov
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Corresponding author

Correspondence to B. A. Trofimov.

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Lobanova, N.A., Tatarinova, I.V., Ushakov, I.A. et al. Reaction of Nitromethane with Phenylacetylene in Superbasic Medium. Russ J Org Chem 60, 543–547 (2024). https://doi.org/10.1134/S1070428024030242

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