Abstract
The possibility of the coupled electrochemical reduction of carbon dioxide and hydrogen in the presence of 2,2'-bipyridine and its N-substituted salts in the presence of acids with different pKa values was studied. It was found that the strength of the acid affects the efficiency of the process; in particular, methylsulfonic acid promotes the coupled hydrogen formation and the reduction of carbon dioxide to formic acid. Plausible mechanisms of the reactions that occurred have been proposed.
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REFERENCES
Jenkinson, D.S., Adams, D.E., and Wild, A., Nature, 1991, vol. 351. p. 304. https://doi.org/10.1038/351304a0
Weimer, T., Schaber, K., Specht, M., and Bansi, A., Energy Convers. Manag., 1996, vol. 370020, p. 1351. https://doi.org/10.1016/0196-8904(95)00345-2
Liu, J.-L., Wang, X., Li, X.-S., Likozar, B., and Zhu, A.-M., J. Phys. D Appl. Phys., 2020, vol. 53, p. 253001. https://doi.org/10.1088/1361-6463/ab7c04
Jessop, P.G., Joó, F., and Tai, C.-C., Coord. Chem. Rev., 2004, vol. 248, p. 2425. https://doi.org/10.1016/j.ccr.2004.05.019
Glockler, G., Phys. Chem., 1958, vol. 62, p. 1049. https://doi.org/10.1021/j150567a006
Tanaka, K., BCSJ, 1998, vol. 71, p. 17. https://doi.org/10.1246/bcsj.71.17
Ren, S., Joulié, D., Salvatore, D., Torbensen, K., Wang, M., Robert, M., and Berlinguette, C.P., Science, 2019, vol. 365, p. 367. https://doi.org/10.1126/science.aax4608
Jin, S., Hao, Z., Zhang, K., Yan, Z., and Chen, J., Angew. Chem., 2021, vol. 133, p. 20795. https://doi.org/10.1002/ange.202101818
Zhu, D.D., Liu, J.L., and Qiao, S.Z., Adv. Mater., 2016, vol. 28, p. 3423. https://doi.org/10.1002/adma.201504766
Alberico, E. and Nielsen, M., Chem. Commun., 2015, vol. 51, p. 6714. https://doi.org/10.1039/C4CC09471A
Dong, K. Razzaq, R., Hu, Y., and Ding, K., Top Curr. Chem., 2017, vol. 375, p. 23. https://doi.org/10.1007/s41061-017-0107-x
Qiao, J., Liu, Y., Hong, F., and Zhang, J., Chem. Soc. Rev., 2014, vol. 43, p. 631. https://doi.org/10.1039/C3CS60323G
Zheng, Y., Vasileff, A., Zhou, X., Jiao, Y., Jaroniec, M., and Qiao, S.-Z., J. Am. Chem. Soc., 2019, vol. 141, p. 7646. https://doi.org/10.1021/jacs.9b02124
Boutin, E. and Robert, M., Trends Chem., 2021, vol. 3, p. 359. https://doi.org/10.1016/j.trechm.2021.02.003
Lim, R. J., Xie, M., Sk, M.A., Lee, J.-M., Fisher, A., Wang, X., and Lim, K.H., Catal. Today, 2014, vol. 233, p. 169. https://doi.org/10.1016/j.cattod.2013.11.037
Specht, M., Staiss, F., Bandi, A., and Weimer, T., Int. J. Hydrog. Energy, 1998, vol. 23, p. 387. https://doi.org/10.1016/S0360-3199(97)00077-3
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The work was financially supported by the Ministry of Science and Higher Education of the Russian Federation (subject no. 121111000064-5) in the framework of the state assignment for the Ogarev Mordovian State National Research University (creation of new youth laboratories).
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Translated from Zhurnal Organicheskoi Khimii, 2023, Vol. 59, No. 11, pp. 1482–1488 https://doi.org/10.31857/S0514749223110095.
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Okina, E.V., Klimaeva, L.A., Chugunov, D.B. et al. Coupled Electrochemical Reduction of CO2 and H+ in the Presence of Substituted 2,2'-Bipyridinium Salts. Russ J Org Chem 59, 1916–1921 (2023). https://doi.org/10.1134/S107042802311009X
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DOI: https://doi.org/10.1134/S107042802311009X