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Microwave Activation in the [FeCl3·6H2O–TfOH]-Catalyzed Reaction of Binor-S with Organic Nitriles

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Abstract

An efficient catalytic system consisting of 20 mol % FeCl3·6H2O and 20 mol % trifluoromethane­sulfonic acid has been developed for the amidation of binor-S with organic nitriles in toluene under microwave irradiation. The reaction is generally carried out at 100°C and is complete in 15 min.

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CONFLICT OF INTEREST

The authors declare the absence of conflict of interest.

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ACKNOWLEDGMENTS

The spectral and analytical data were obtained using the facilities of the Agidel regional joint center, Ufa Federal Research Center, Russian Academy of Sciences.

Funding

This study was performed under financial support by the Russian Foundation for Basic Research (project no. 19-33-60046). Binor-S was synthesized in the framework of state assignment of the Ministry of Science and Higher Education of the Russian Federation (project no. FMRS-2022-0076).

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences, 450075, Ufa, Russia

    K. S. Frolova, T. P. Zosim, A. V. Akhmerova & I. R. Ramazanov

Authors
  1. K. S. Frolova
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  2. T. P. Zosim
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  3. A. V. Akhmerova
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  4. I. R. Ramazanov
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Corresponding author

Correspondence to K. S. Frolova.

Additional information

Translated from Zhurnal Organicheskoi Khimii, 2023, Vol. 59, No. 9, pp. 1209–1216 https://doi.org/10.31857/S0514749223090100.

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Frolova, K.S., Zosim, T.P., Akhmerova, A.V. et al. Microwave Activation in the [FeCl3·6H2O–TfOH]-Catalyzed Reaction of Binor-S with Organic Nitriles. Russ J Org Chem 59, 1537–1542 (2023). https://doi.org/10.1134/S1070428023090105

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  • DOI: https://doi.org/10.1134/S1070428023090105

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