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Silicon Analogs of Unsaturated Hydrocarbons

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Abstract

The existing fundamental similarities in the chemistry of structurally related carbon and silicon compounds have been demonstrated. Stable silicon analogs of ethylene, silenes or silaethylenes R2C=SiR2 and disilenes R2Si=SiR2, as well as ethyne (acetylene) analogs, disilynes RSi≡SiR, have been considered. A number of unique branched (bulky) organic and organosilicon substituents have been described; the introduction of such substituents to double- or triple-bonded silicon atoms makes it possible to protect the latter from the action of atmospheric oxygen and moisture and prevent secondary dimerization (oligomerization) processes. Examples are given of steric protection for obtaining kinetically stable unsaturated silicon compounds which were characterized by IR, NMR, and UV-Vis spectroscopy and X-ray analysis.

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CONFLICT OF INTEREST

The authors declare the absence of conflict of interest in the financial or any other sphere.

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Funding

This study was performed in the framework of state assignment no. FFSE-2023-0005 “Organic, Organoelement, and Coordination Compounds as Components of Materials for Modern High Technologies” (reg. no. 123031000051-4).

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603950, Nizhny Novgorod, Russia

    V. V. Semenov & N. V. Zolotareva

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  1. V. V. Semenov
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  2. N. V. Zolotareva
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Correspondence to V. V. Semenov.

Additional information

Translated from Zhurnal Organicheskoi Khimii, 2023, Vol. 59, No. 9, pp. 1111–1120 https://doi.org/10.31857/S051474922309001X.

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Semenov, V.V., Zolotareva, N.V. Silicon Analogs of Unsaturated Hydrocarbons. Russ J Org Chem 59, 1457–1464 (2023). https://doi.org/10.1134/S1070428023090014

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  • DOI: https://doi.org/10.1134/S1070428023090014

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