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ZnFe2O4@SiO2–SO3H Magnetic Nanoparticles: A New, Efficient, and Recyclable Heterogeneous Nanocatalyst for Successful Synthesis of 5-Substituted-1H-tetrazoles

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Abstract

A simple and efficient procedure for the synthesis of 5-substituted-1H-tetrazoles via the [3+2] cycloaddition reaction of nitriles with sodium azide was developed. The reaction occurred in DMF at 120°C in the presence of a reusable and an environmentally friendly ZnFe2O4@SiO2–SO3H heterogeneous magnetic nanocatalyst prepared in the present work. The new catalytic system was characterized by FTIR spectroscopy, field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray (EDX) spectroscopy, and vibrating sample magnetometry (VSM). The results showed that the ZnFe2O3@SiO2–SO3H nanoparticles are highly efficient for this organic reaction. The methodology offers such benefits as quick reaction, high yields of the desired product, clean process, as well as the low-cost heterogeneous catalyst and its low loading, simple separation, and recyclability.

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CONFLICT OF INTEREST

The authors declare no conflict of interest.

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Authors and Affiliations

  1. Chemistry Department, Payame Noor University, 19395-4697, Tehran, Iran

    Azadeh Nozari & Hassan Hassani

  2. Department of Chemistry, Faculty of Sciences, University of Gonabad, 9691957678, Gonabad, Iran

    Azam Karimian

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  1. Azadeh Nozari
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Nozari, A., Hassani, H. & Karimian, A. ZnFe2O4@SiO2–SO3H Magnetic Nanoparticles: A New, Efficient, and Recyclable Heterogeneous Nanocatalyst for Successful Synthesis of 5-Substituted-1H-tetrazoles. Russ J Org Chem 59, 1370–1381 (2023). https://doi.org/10.1134/S1070428023080122

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