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Synthesis of Triethylene Glycol-Substituted Phenylterpyridine with a Terminal Aurophilic Group and Its Rh(III) Complex for Adsorption on the Gold Surface

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Abstract

A method for the synthesis of a conjugate of 4-substituted phenylterpyridine and lipoic acid, containing a triethylene glycol linker group between the terpyridine and sulfur-containing fragments, has been developed. A coordination compound of the resulting terpyridine with Rh(III) was obtained. Cyclic voltammetry was used to explore the ability of the synthesized ligand and its rhodium complex to be chemisorbed on the surface of gold electrodes to form an Au–S bond.

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Authors and Affiliations

  1. Lomonosov Moscow State University, 119991, Moscow, Russia

    I. O. Salimova, A. A. Moiseeva, N. V. Zyk & E. K. Beloglazkina

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  1. I. O. Salimova
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  2. A. A. Moiseeva
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  3. N. V. Zyk
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  4. E. K. Beloglazkina
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Correspondence to E. K. Beloglazkina.

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Translated from Zhurnal Organicheskoi Khimii, 2023, Vol. 59, No. 5, pp. 616–624 https://doi.org/10.31857/S0514749223050087.

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Salimova, I.O., Moiseeva, A.A., Zyk, N.V. et al. Synthesis of Triethylene Glycol-Substituted Phenylterpyridine with a Terminal Aurophilic Group and Its Rh(III) Complex for Adsorption on the Gold Surface. Russ J Org Chem 59, 793–800 (2023). https://doi.org/10.1134/S1070428023050081

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  • DOI: https://doi.org/10.1134/S1070428023050081

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