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Synthesis of Phosphoryl-Substituted Cyclopropanes by Reaction of (1-Bromoethenyl)(diphenyl)phosphine Oxide with CH Acids

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Abstract

Phosphoryl-substituted cyclopropane derivatives were synthesized by reaction of (1-bromoethenyl)­(diphenyl)phosphine oxide with CH acids such as acetylacetone, ethyl acetoacetate, and diethyl malonate in the presence of sodium hydroxide (reactant ratio 1:2:3) in acetonitrile at room temperature.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry, National Academy of Sciences of Armenia, 0014, Yerevan, Armenia

    G. Ts. Gasparyan, M. Zh. Ovakimyan, A. S. Poghosyan, A. S. Bichakhchyan & L. V. Derdzyan

  2. Molecular Structure Research Center, Scientific Technological Center of Organic and Pharmaceutical Chemistry, National Academy of Sciences of Armenia, 0014, Yerevan, Armenia

    H. A. Panosyan

Authors
  1. G. Ts. Gasparyan
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  2. M. Zh. Ovakimyan
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  3. A. S. Poghosyan
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  4. A. S. Bichakhchyan
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  5. L. V. Derdzyan
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  6. H. A. Panosyan
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Corresponding author

Correspondence to A. S. Bichakhchyan.

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Gasparyan, G.T., Ovakimyan, M.Z., Poghosyan, A.S. et al. Synthesis of Phosphoryl-Substituted Cyclopropanes by Reaction of (1-Bromoethenyl)(diphenyl)phosphine Oxide with CH Acids. Russ J Org Chem 58, 1989–1991 (2022). https://doi.org/10.1134/S1070428022120314

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  • DOI: https://doi.org/10.1134/S1070428022120314

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