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Synthesis of Fullerene C60 Hybrids with Catecholamines under Ultrasonic Irradiation

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Abstract

Morpholine–fullerene C60 monoadducts were synthesized for the first time by reaction of C60 with biogenic amines (noradrenaline and adrenaline) under ultrasonic irradiation in toluene/DMF at room temperature on exposure to air. The key intermediate in the synthesis of the C60–adrenaline cycloadduct, C60 radical anion generated by single-electron transfer from the adrenaline molecule to C60, was detected by ESR (C60‒·, g = 2.0000, ΔH1/2 = 3.2 G).

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ACKNOWLEDGMENTS

Structural studies were performed at the Agidel joint center, Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences. The ESR spectra were recorded at the Spectrum joint center, Institute of Molecular and Crystal Physics, Ufa Federal Research Center, Russian Academy of Sciences.

Funding

This study was financially supported in the framework of state assignment no. FMRS-2022-0077.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences, 450075, Ufa, Russia

    Z. S. Kinzyabaeva & D. Sh. Sabirov

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  1. Z. S. Kinzyabaeva
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  2. D. Sh. Sabirov
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Correspondence to Z. S. Kinzyabaeva.

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Kinzyabaeva, Z.S., Sabirov, D.S. Synthesis of Fullerene C60 Hybrids with Catecholamines under Ultrasonic Irradiation. Russ J Org Chem 58, 1915–1919 (2022). https://doi.org/10.1134/S1070428022120223

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