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Trifluoroethoxylation of Styrenes via Photoredox-Catalyzed Meerwein Reaction

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An Erratum to this article was published on 01 October 2022

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Abstract

In recent years, visible-light photoredox catalysis has become a widely used synthetic method. Photoredox-catalyzed Meerwein reaction of styrenes in the presence of 2,2,2-trifluoroethanol as a nucleophile afforded the target aryl trifluoroethoxylation products in moderate yields 32–53%. The best results were achieved using [Ru(bpy)3](PF6)2 as a catalyst in the presence of Na2HPO4 in acetonitrile.

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Funding

This study was performed under financial support by the Russian Science Foundation [project nos. 20-73-00103 (optimization of the conditions, synthesis of 1, 2, 8–10), 19-13-00223P (synthesis of 3–7)].

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia

    A. D. Kharlamova, A. S. Abel, A. D. Averin & I. P. Beletskaya

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    A. S. Abel, A. D. Averin & I. P. Beletskaya

Authors
  1. A. D. Kharlamova
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  2. A. S. Abel
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  3. A. D. Averin
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  4. I. P. Beletskaya
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Correspondence to A. S. Abel.

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Additional information

Translated from Zhurnal Organicheskoi Khimii, 2022, Vol. 58, No. 9, pp. 913–925 https://doi.org/10.31857/S0514749222090014.

The original online version of this article was revised: The authors of this article are A.D. Kharlamova, A.S. Abel, A.D. Averin, and I.P. Beletskaya, and A.S. Abel is the corresponding author.

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Kharlamova, A.D., Abel, A.S., Averin, A.D. et al. Trifluoroethoxylation of Styrenes via Photoredox-Catalyzed Meerwein Reaction. Russ J Org Chem 58, 1181–1191 (2022). https://doi.org/10.1134/S1070428022090019

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