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Synthesis of 3-(Organyloxymethyl)oxazolidines

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Abstract

The condensation/heterocyclization of 2-aminoethanol with formaldehyde and various alcohols afforded 3-(organyloxymethyl)-1,3-oxazolidines. Their yields depended on the nature of the hydroxy compound and increased in parallel with its size. 3,3′-Methylenebis(1,3-oxazolidine) was formed as by-product; it was also synthesized independently by the condensation of 2-aminoethanol with formaldehyde at a ratio of 2:3. Physico­chemical characteristics and 13C NMR spectra of the synthesized compounds are given. NMR signals were assigned using 13C–{1H} heteronuclear double-resonance technique.

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Authors and Affiliations

  1. Kuliev Institute of Chemistry of Additives, National Academy of Sciences of Azerbaijan, 1029, Baku, Azerbaijan

    V. M. Farzaliev, M. T. Abbasova, Z. K. Soltanova & L. R. Safarova

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  1. V. M. Farzaliev
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  2. M. T. Abbasova
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  3. Z. K. Soltanova
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  4. L. R. Safarova
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Correspondence to M. T. Abbasova.

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Farzaliev, V.M., Abbasova, M.T., Soltanova, Z.K. et al. Synthesis of 3-(Organyloxymethyl)oxazolidines. Russ J Org Chem 58, 800–804 (2022). https://doi.org/10.1134/S1070428022060069

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  • DOI: https://doi.org/10.1134/S1070428022060069

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