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Hydrogenation of 3-Methyl-3-buten-1-yl Acetate to Alcohols in the Presence of Bimetallic Cu˗Pt Catalysts

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Abstract

The catalytic synthesis of isoprenol by hydrogenation of 3-methylbut-3-en-1-yl acetate on heterogeneous bimetallic Cu-Pt catalysts was carried out for the first time. The best selectivity of isoprenol (76%) was obtained on the 5%Cu–1%Pt/SiO2 catalyst with a full ester conversion in 6 h of the reaction.

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Funding

The research was financially supported by the Ministry of Science and Higher Education of the Russian Federation (project no. 075-15-2021-978).

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Authors and Affiliations

  1. MISiS National University of Science and Technology, 119991, Moscow, Russia

    A. A. Strekalova, A. A. Shesterkina, E. V. Shuvalova & L. M. Kustov

  2. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. A. Strekalova, A. A. Shesterkina & L. M. Kustov

  3. Instituto de Química, Universidade Estadual de Campinas, 13083-970, Campinas, Brazil

    C. R. D. Correia

  4. Tsinghua University, 100084, Beijing, China

    Boqing Xu

  5. East China University of Science and Technology, 200237, Shanghai, China

    Xuezhi Duan

  6. School of Chemical Engineering, Nanjing University of Technology, 210094, Nanjing, China

    Yanhui Yang

  7. Chemistry Department, Lomonosov Moscow State University, 119992, Moscow, Russia

    L. M. Kustov

Authors
  1. A. A. Strekalova
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  2. A. A. Shesterkina
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  3. E. V. Shuvalova
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  4. C. R. D. Correia
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  5. Boqing Xu
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  6. Xuezhi Duan
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  7. Yanhui Yang
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  8. L. M. Kustov
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Corresponding author

Correspondence to A. A. Strekalova.

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The authors declare no conflict of interest.

Additional information

Translated from Zhurnal Organicheskoi Khimii, 2022, Vol. 58, No. 5, pp. 543–547 https://doi.org/10.31857/S0514749222050123.

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Strekalova, A.A., Shesterkina, A.A., Shuvalova, E.V. et al. Hydrogenation of 3-Methyl-3-buten-1-yl Acetate to Alcohols in the Presence of Bimetallic Cu˗Pt Catalysts. Russ J Org Chem 58, 720–723 (2022). https://doi.org/10.1134/S1070428022050128

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  • DOI: https://doi.org/10.1134/S1070428022050128

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