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Reaction of 5,5′-Diaryl-1,1′-dihydroxy-2,2′-biimidazoles with Trimethyl Phosphite

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Abstract

The reaction of 5,5′-diaryl-1H,1H-[2,2′-biimidazole]-1,1′-diols with trimethyl phosphite gave the cor­responding 4′,5-diaryl-1′,4,5′-trimethyl-1H,1′H-[2,2′-biimidazol]-1-ols and 4,5′-diaryl-1,4′,5-trimethyl-1H,1′H-2,2′-biimidazoles. The structure of the synthesized compounds was determined using various NMR correlation techniques (1H–1H COSY, 1H–13C HSQC, 1H–13C HMBC, 1H–1H NOESY).

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ACKNOWLEDGMENTS

The authors thank the joint chemical service center, Siberian Branch, Russian Academy of Sciences, for performing spectral and analytical studies.

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Authors and Affiliations

  1. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    V. I. Krasnov, I. A. Os’kina & A. Ya. Tikhonov

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  1. V. I. Krasnov
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  2. I. A. Os’kina
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  3. A. Ya. Tikhonov
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Correspondence to I. A. Os’kina.

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Translated from Zhurnal Organicheskoi Khimii, 2022, Vol. 58, No. 1, pp. 89–95 https://doi.org/10.31857/S0514749222010098.

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Krasnov, V.I., Os’kina, I.A. & Tikhonov, A.Y. Reaction of 5,5′-Diaryl-1,1′-dihydroxy-2,2′-biimidazoles with Trimethyl Phosphite. Russ J Org Chem 58, 70–75 (2022). https://doi.org/10.1134/S1070428022010092

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  • DOI: https://doi.org/10.1134/S1070428022010092

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