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Convenient Synthesis of Symmetrical Polyfluorinated Diphenyl Sulfides

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Abstract

Thermal properties of decafluorodiphenyl disulfide in the pure state and in the presence of copper and iron metals have been studied. A procedure has been proposed for the synthesis of symmetrical poly­fluorinated diaryl sulfides from diaryl disulfides by heating with iron at high temperature. The developed procedure has been utilized to obtain 1,1′-sulfanediylbis(pentafluorobenzene), 1,1′-sulfanediylbis[3,5,6-tri­fluoro-2,4-bis(trifluoromethyl)benzene], and some other symmetrical polyfluorinated diphenyl sulfides containing a hydrogen or chlorine atom or trifluoromethyl group at the para positions of the benzene rings in up to 84% yield.

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ACKNOWLEDGMENTS

Analytical and spectral data were obtained by the staff of the Multi-Access Chemical Research Center, Siberian Branch, Russian Academy of Sciences.

Funding

This study was performed in the framework of state assignment no. 0238-2021-0002.

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Authors and Affiliations

  1. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    P. V. Nikul’shin, R. A. Bredikhin, A. M. Maksimov & V. E. Platonov

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  1. P. V. Nikul’shin
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  2. R. A. Bredikhin
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  3. A. M. Maksimov
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  4. V. E. Platonov
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Correspondence to A. M. Maksimov.

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The authors declare the absence of conflict of interest.

Additional information

Translated from Zhurnal Organicheskoi Khimii, 2021, Vol. 57, No. 12, pp. 1694–1705 https://doi.org/10.31857/S0514749221120041.

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Nikul’shin, P.V., Bredikhin, R.A., Maksimov, A.M. et al. Convenient Synthesis of Symmetrical Polyfluorinated Diphenyl Sulfides. Russ J Org Chem 57, 1921–1930 (2021). https://doi.org/10.1134/S1070428021120046

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  • DOI: https://doi.org/10.1134/S1070428021120046

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