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Cascade Transformations of [1,2,3]Triazolo[1,5-a]pyridines as Convenient Precursors of Diazo Compounds and Metal Carbenes

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Abstract

The review is devoted to the use of [1,2,3]triazolo[1,5-a]pyridines as precursors of tautomeric 2-(diazomethyl)pyridines. This methodology represents a convenient tool for the synthesis of various types of nitrogen-containing heterocycles. Both noncatalytic transformations and cascade reactions involving metal carbenes, which have been intensively studied in recent years, are considered. Major approaches to the preparation of [1,2,3]triazolo[1,5-a]pyridines are also summarized in the review.

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The work was financially supported by the Russian Science Foundation (project no. 19-73-00184).

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  1. Chemistry Department, Lomonosov Moscow State University, 119991, Moscow, Russia

    Y. N. Kotovshchikov, V. A. Voloshkin, G. V. Latyshev, N. V. Lukashev & I. P. Beletskaya

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Translated from Zhurnal Organicheskoi Khimii, 2021, Vol. 57, No. 8, pp. 1084–1119 https://doi.org/10.31857/S0514749221080024.

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Kotovshchikov, Y.N., Voloshkin, V.A., Latyshev, G.V. et al. Cascade Transformations of [1,2,3]Triazolo[1,5-a]pyridines as Convenient Precursors of Diazo Compounds and Metal Carbenes. Russ J Org Chem 57, 1212–1244 (2021). https://doi.org/10.1134/S1070428021080029

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