Skip to main content
Log in

N,N-Bis(cyanomethyl)trifluoromethanesulfonamide

  • Published:
Russian Journal of Organic Chemistry Aims and scope Submit manuscript

Abstract

Trifluoromethanesulfonamide and its sodium salt reacted with bromoacetonitrile to give a mixture of N-(cyanomethyl)trifluoromethanesulfonamide and N,N-bis(cyanomethyl)trifluoromethanesulfonamide at ratios of 1:1 and 1:14, respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Scheme
Scheme

REFERENCES

  1. Makosza, M., Chem. Soc. Rev., 2010, vol. 39, p. 2855. https://doi.org/10.1039/B822559C

    Article  CAS  PubMed  Google Scholar 

  2. Velcicky, J., Soicke, A., Steiner, R., and Schmalz, H.-G.,J. Am. Chem. Soc., 2011, vol. 133, p. 6948. https://doi.org/10.1021/ja201743j

    Article  CAS  PubMed  Google Scholar 

  3. Jinzaki, T., Arakawa, M., Kinoshita, H., Ichikawa, J., and Miura, K., Org. Lett., 2013, vol. 15, p. 3750. https://doi.org/10.1021/ol401663u

    Article  CAS  PubMed  Google Scholar 

  4. López, R. and Palomo, C., Angew. Chem., Int. Ed., 2015, vol. 54, p. 13170. https://doi.org/10.1002/anie.201502493

    Article  CAS  Google Scholar 

  5. Shainyan, B.A. and Tolstikova, L.L., Chem. Rev., 2013, vol. 113, p. 699. https://doi.org/10.1021/cr300220h

    Article  CAS  PubMed  Google Scholar 

  6. Amos, D.T., Renslo, A.R., and Danheiser, R.L., J. Am. Chem. Soc., 2003, vol. 121, p. 4970. https://doi.org/10.1021/ja034629o

    Article  CAS  Google Scholar 

  7. Maloney, K.M. and Danheiser, R.L., Org. Lett., 2005, vol. 7, p. 3115. https://doi.org/10.1021/ol051185n

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  8. Zhang, C.-P., Wang, Z.-L., Chen, Q.-Y., Zhang, C.-T., Gu, Y.-C., and Xiao, J.-C., J. Fluorine Chem., 2010, vol. 131, p. 761. https://doi.org/10.1016/j.jfluchem.2010.03.013

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

This study was performed using the facilities of the Baikal joint center, Siberian Branch, Russian Academy of Sciences.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to L. L. Tolstikova.

Ethics declarations

The authors declare the absence of conflict of interest.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Tolstikova, L.L., Shainyan, B.A. N,N-Bis(cyanomethyl)trifluoromethanesulfonamide. Russ J Org Chem 56, 716–718 (2020). https://doi.org/10.1134/S1070428020040235

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070428020040235

Keywords:

Navigation