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Catalytic Synthesis of N-Aryl-1,5,3-dithiazocanes

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Abstract

An efficient procedure has been developed for the synthesis of N-aryl-1,5,3-dithiazocanes and 1,1′-biphenylenebis(1,5,3-dithiazocanes) by heterocyclization of N1,N1,N7,N7-tetramethyl-2,6-dithiaheptane-1,7-diamine with aromatic amines or 4,4′-methylene(or sulfonyl)dianiline in the presence of Sm(NO3)3·6H2O as catalyst.

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ACKNOWLEDGMENTS

The spectral and analytical data were obtained using the facilities of the Agidel joint center (Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences).

Funding

This study was performed in accordance with the research program of the Institute of Petrochemistry and Catalysis (Ufa Federal Research Center, Russian Academy of Sciences; project no. AAAA-A19-119022290010-9 for 2019–2021 “Metal Complex and Heterogeneous Catalysis in the Synthesis of Macroheterocycles and Heteroatom Compounds”), as well as under financial support by the Ministry of Science and Education of the Russian Federation (project no. 2019-05-595-000-058).

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences, 450075, Ufa, Russia

    E. B. Rakhimova, I. V. Ozden & A. G. Ibragimov

Authors
  1. E. B. Rakhimova
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  2. I. V. Ozden
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  3. A. G. Ibragimov
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Corresponding author

Correspondence to E. B. Rakhimova.

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The authors declare the absence of conflict of interest.

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Rakhimova, E.B., Ozden, I.V. & Ibragimov, A.G. Catalytic Synthesis of N-Aryl-1,5,3-dithiazocanes. Russ J Org Chem 56, 544–547 (2020). https://doi.org/10.1134/S107042802003029X

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  • DOI: https://doi.org/10.1134/S107042802003029X

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