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Uncatalyzed Hydrodechlorination of Dichlorobiphenyls

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Abstract

Mono-, di-, and trichlorobiphenyls showed different reactivities toward alkali in 2-aminoethanol under reflux: 3-chlorobiphenyl remained unchanged, 2,4,5- and 2,4′,5-trichlorobiphenyls were completely converted to hydroxy derivatives, whereas 3,4-dichlorobiphenyl and a mixture of 2,4′-, 3,4′-, and 4,4′-dichlorobiphenyls gave rise to chlorobiphenyls in addition to hydroxybiphenyls.

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Acknowledgments

The study was performed using the equipment of the “Spectroscopy and Analysis of Organic Compounds” joint center.

Funding

This study was performed in the framework of state assignment № 075-00578-19-00.

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Authors and Affiliations

  1. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia

    T. I. Gorbunova, M. G. Pervova, V. I. Saloutin & O. N. Chupakhin

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  1. T. I. Gorbunova
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  2. M. G. Pervova
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  3. V. I. Saloutin
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  4. O. N. Chupakhin
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Corresponding author

Correspondence to T. I. Gorbunova.

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Conflict of Interests

The authors declare the absence of conflict of interests.

Russian Text © The Author(s), 2019, published in Zhurnal Organicheskoi Khimii, 2019, Vol. 55, No. 7, pp. 1089–1092.

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Gorbunova, T.I., Pervova, M.G., Saloutin, V.I. et al. Uncatalyzed Hydrodechlorination of Dichlorobiphenyls. Russ J Org Chem 55, 988–990 (2019). https://doi.org/10.1134/S1070428019070121

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  • DOI: https://doi.org/10.1134/S1070428019070121

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