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Russian Journal of Organic Chemistry

, Volume 55, Issue 5, pp 707–715 | Cite as

Recognition and Sensing of Guanidine-containing Biomolecules in Aqueous Medium

  • Subrata JanaEmail author
  • Kishor Kumar Suryavanshi
Article
  • 14 Downloads

Abstract

A dicarboxylate-based fluorescent receptor has been synthesized for the recognition of the guanidinium ion and guanidine-containing biomolecules in aqueous medium to address the issue of biomolecular interaction. The acyclic receptor binds to guests in a 1: 2 mode due to the flexibility of its binding motifs. The host-guest binding behavior was studied by means of UV and fluorescence titration. The binding of the host with the guanidinium ion was found to be stronger than with the other guanidine-containing guests.

Key words

molecular recognition host-guest fluorescence sensor α,β-unsaturated carbonyl guanidinium ion 

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Notes

Acknowledgments

Subrata Jana thanks to MPCST, Govt. of Madhya Pradesh, India for financial support. Kishor Kumar Suryavanshi thanks to Indira Gandhi National Tribal University (Central University), Amarkantak, M.P., India for research fellowship.

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  1. 1.Department of ChemistryIndira Gandhi National Tribal University (Central University)AmarkantakIndia

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