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Russian Journal of Organic Chemistry

, Volume 55, Issue 5, pp 678–681 | Cite as

Polyaromatic Products of Three-Component Coupling of Aryl Halide with Two Molecules of Arylacetylene and Arylboronic Acid under Ligand-Free Catalysis Conditions

  • E. V. Yarosh
  • E. V. Larina
  • N. A. Lagoda
  • A. A. Kurokhtina
  • A. F. SchmidtEmail author
Article
  • 14 Downloads

Abstract

The aryl halide-arylacetylene-arylboronic acid three-component coupling in the presence of a Pd catalyst containing no organic ligands is described. The reaction routes that take place in the reaction system are shown to include the consecutive carbopalladation of two arylacetylene molecules, leading to unsaturated polyaromatic compounds. The possibility of controlling the alternative reaction routes is demonstrated.

Keywords

three-component coupling polyaromatic compounds catalysis palladium carbopalladation 

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • E. V. Yarosh
    • 1
  • E. V. Larina
    • 1
  • N. A. Lagoda
    • 1
  • A. A. Kurokhtina
    • 1
  • A. F. Schmidt
    • 1
    Email author
  1. 1.Irkutsk State UniversityIrkutskRussia

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