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Role of Prins Reaction and Aminomethylation in the Synthesis of 1,3-Oxazinane from α-Methylstyrene

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Abstract

Study of the mechanism of formation of 1,3-oxazinane in the reaction of α-methylstyrene with formaldehyde and amines in aqueous medium has shown that 3,6-dimethyl-6-phenyl-1,3-oxazinane is formed as a result of transformations of 4-methyl-4-phenyl-1,3-dioxane which is the Prins reaction product.

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Authors and Affiliations

  1. Bashkir State University, ul. Zaki Validi 32, Ufa, Bashkortostan, 450076, Russia

    A. Kh. Fattakhov, R. F. Talipov & G. R. Talipova

Authors
  1. A. Kh. Fattakhov
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  2. R. F. Talipov
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  3. G. R. Talipova
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Corresponding author

Correspondence to A. Kh. Fattakhov.

Additional information

Original Russian Text © A.Kh. Fattakhov, R.F. Talipov, G.R. Talipova, 2018, published in Zhurnal Organicheskoi Khimii, 2018, Vol. 54, No. 12, pp. 1836–1838.

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Fattakhov, A.K., Talipov, R.F. & Talipova, G.R. Role of Prins Reaction and Aminomethylation in the Synthesis of 1,3-Oxazinane from α-Methylstyrene. Russ J Org Chem 54, 1851–1853 (2018). https://doi.org/10.1134/S1070428018120229

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  • DOI: https://doi.org/10.1134/S1070428018120229

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