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One-Pot Synthesis of 1-(1-Alkoxyethoxy)allenes

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Abstract

A convenient one-pot procedure has been proposed for the preparation of 1-(1-alkoxyethoxy)allenes from alkoxyethenes and prop-2-yn-1-ol with the use of trifluoroacetic acid as highly efficient catalyst for the synthesis of 3-(1-alkoxyethoxy)prop-1-ynes and of the system t-BuOK–DMSO for the isomerization of the latter into allenes.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    O. A. Tarasova, N. A. Nedolya & A. I. Albanov

Authors
  1. O. A. Tarasova
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  2. N. A. Nedolya
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  3. A. I. Albanov
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Correspondence to N. A. Nedolya.

Additional information

Original Russian Text © O.A.Tarasova, N.A. Nedolya, A.I. Albanov, 2018, published in Zhurnal Organicheskoi Khimii, 2018, Vol. 54, No. 12, pp. 1817–1820.

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Tarasova, O.A., Nedolya, N.A. & Albanov, A.I. One-Pot Synthesis of 1-(1-Alkoxyethoxy)allenes. Russ J Org Chem 54, 1831–1834 (2018). https://doi.org/10.1134/S1070428018120163

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  • DOI: https://doi.org/10.1134/S1070428018120163

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