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First Example of the Aza-Favorskii Reaction. Ethynylation of C=N Bond in the Superbasic System t-BuOK–DMSO

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Abstract

Direct ethynylation of ketimines with alkynes in the superbasic system t-BuOK–DMSO has been accomplished for the first time using the reaction of (E)-N,1-diphenylethan-1-imine with 3-ethynylaniline as an example.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    I. A. Bidusenko, E. Yu. Schmidt & B. A. Trofimov

Authors
  1. I. A. Bidusenko
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  2. E. Yu. Schmidt
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  3. B. A. Trofimov
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Corresponding author

Correspondence to B. A. Trofimov.

Additional information

Original Russian Text © I.A. Bidusenko, E.Yu. Schmidt, B.A. Trofimov, 2018, published in Zhurnal Organicheskoi Khimii, 2018, Vol. 54, No. 9, pp. 1406–1407.

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Bidusenko, I.A., Schmidt, E.Y. & Trofimov, B.A. First Example of the Aza-Favorskii Reaction. Ethynylation of C=N Bond in the Superbasic System t-BuOK–DMSO. Russ J Org Chem 54, 1422–1424 (2018). https://doi.org/10.1134/S1070428018090269

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  • DOI: https://doi.org/10.1134/S1070428018090269

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