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Ethoxytelluration of Terminal Alkenes with Tellurium Tetrahalides

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Abstract

Efficient methods for the preparation of trichloro- and tribromo(2-ethoxyalkyl)-λ4-tellanes in 80 to 100% yield have been developed on the basis of ethoxytelluration of hex-1-ene, hept-1-ene, and oct-1-ene with tellurium tetrahalides. Tribromo(2-ethoxyalkyl)-λ4-tellanes have been reduced to 1,2-bis(2-ethoxyalkyl)ditellanes in 92–95% yield with the system NaBH4–H2O–THF.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    M. V. Musalova, M. V. Musalov, S. I. Udalova, A. G. Khabibulina, A. I. Albanov, V. A. Potapov & S. V. Amosova

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  1. M. V. Musalova
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  2. M. V. Musalov
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  3. S. I. Udalova
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  4. A. G. Khabibulina
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  5. A. I. Albanov
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  6. V. A. Potapov
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  7. S. V. Amosova
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Corresponding author

Correspondence to S. V. Amosova.

Additional information

Original Russian Text © M.V. Musalova, M.V. Musalov, S.I. Udalova, A.G. Khabibulina, A.I. Albanov, V.A. Potapov, S.V. Amosova, 2018, published in Zhurnal Organicheskoi Khimii, 2018, Vol. 54, No. 9, pp. 1279–1282.

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Musalova, M.V., Musalov, M.V., Udalova, S.I. et al. Ethoxytelluration of Terminal Alkenes with Tellurium Tetrahalides. Russ J Org Chem 54, 1290–1293 (2018). https://doi.org/10.1134/S1070428018090038

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  • DOI: https://doi.org/10.1134/S1070428018090038

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