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Design of Postmetallocene Catalytic Systems of Arylimine Type for Olefin Polymerization: XVIII. Synthesis of N-Arylsalicylaldimine Ligands Containing meta-or para-Diallylamino Group and Their Titanium(IV) Complexes

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Abstract

Salicylaldehydes containing a tert-butyl or 2-phenylpropan-2-yl group in the 3-position reacted with N,N-diallyl-p-and -m-phenylenediamines in methanol to give the corresponding Schiff bases which were used as ligands to obtain titanium(IV) complexes with the composition L2TiCl2 by reaction with diisopropoxytitanium dichloride.

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Authors and Affiliations

  1. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090, Russia

    I. V. Oleynik & I. I. Oleynik

  2. Novosibirsk State University, ul. Pirogova 1, Novosibirsk, 630090, Russia

    I. V. Oleynik & I. I. Oleynik

Authors
  1. I. V. Oleynik
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  2. I. I. Oleynik
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Correspondence to I. I. Oleynik.

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Original Russian Text © I.V. Oleynik, I.I. Oleynik, 2018, published in Zhurnal Organicheskoi Khimii, 2018, Vol. 54, No. 4, pp. 539–545.

For communication XVII, see [1].

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Oleynik, I.V., Oleynik, I.I. Design of Postmetallocene Catalytic Systems of Arylimine Type for Olefin Polymerization: XVIII. Synthesis of N-Arylsalicylaldimine Ligands Containing meta-or para-Diallylamino Group and Their Titanium(IV) Complexes. Russ J Org Chem 54, 537–544 (2018). https://doi.org/10.1134/S1070428018040048

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  • DOI: https://doi.org/10.1134/S1070428018040048

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