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Alkoxytelluration of Allylbenzene

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Abstract

(2-Alkoxy-3-phenylpropyl)trichlorotellanes were synthesized by regioselective reaction of tellurium tetrachloride with allylbenzene in the system MeOH–CH2Cl2, as well as by nucleophilic substitution of chlorine in trichloro(2-chloro-3-phenylpropyl)tellane in MeOH–CH2Cl2 and EtOH–CHCl3. Allylbenzene reacted with tellurium tetrabromide on heating in methanol or ethanol. The reduction of (2-alkoxy-3-phenylpropyl) trihalotellanes with NaBH4 in H2O–THF gave 1,2-bis(2-alkoxy-3-phenylpropyl)ditellanes.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    M. V. Musalova, M. V. Musalov, S. I. Udalova, A. G. Khabibulina, A. I. Albanov, V. A. Potapov & S. V. Amosova

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  1. M. V. Musalova
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  2. M. V. Musalov
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  3. S. I. Udalova
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  4. A. G. Khabibulina
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  5. A. I. Albanov
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  6. V. A. Potapov
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  7. S. V. Amosova
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Corresponding author

Correspondence to S. V. Amosova.

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Original Russian Text © M.V. Musalova, M.V. Musalov, S.I. Udalova, A.G. Khabibulina, A.I. Albanov, V.A. Potapov, S.V. Amosova, 2018, published in Zhurnal Organicheskoi Khimii, 2018, Vol. 54, No. 4, pp. 528–531.

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Musalova, M.V., Musalov, M.V., Udalova, S.I. et al. Alkoxytelluration of Allylbenzene. Russ J Org Chem 54, 526–529 (2018). https://doi.org/10.1134/S1070428018040024

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  • DOI: https://doi.org/10.1134/S1070428018040024

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