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Synthesis of diamantane via skeletal isomerization of hydrogenated cyclohepta-1,3,5-triene dimers in ionic liquid [Et3NH]+ [Al2Cl7]–

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Abstract

Diamantane was synthesized in 91–97% yield by skeletal isomerization of a mixture of hydrogenated cyclohepta-1,3,5-triene dimers, pentacyclo[8.4.0.03,7.04,14.06,11]tetradecane and pentacyclo-[7.5.0.02,8.05,14.07,11]tetradecane, at a ratio of 3: 2 in the presence of ionic liquid [Et3NH]+ [Al2Cl7]–.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, Ufa, 450075 Bashkortostan, Russia

    R. I. Aminov & R. I. Khusnutdinov

Authors
  1. R. I. Aminov
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  2. R. I. Khusnutdinov
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Correspondence to R. I. Aminov.

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Original Russian Text © R.I. Aminov, R.I. Khusnutdinov, 2017, published in Zhurnal Organicheskoi Khimii, 2017, Vol. 53, No. 12, pp. 1845–1847.

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Aminov, R.I., Khusnutdinov, R.I. Synthesis of diamantane via skeletal isomerization of hydrogenated cyclohepta-1,3,5-triene dimers in ionic liquid [Et3NH]+ [Al2Cl7]–. Russ J Org Chem 53, 1881–1883 (2017). https://doi.org/10.1134/S107042801712017X

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  • DOI: https://doi.org/10.1134/S107042801712017X

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