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Unexpected reaction of 2-bromomethyl-1,3-thiaselenole with formation of bis[(Z)-2-(vinylsulfanyl)ethenyl] diselenide

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Abstract

The reaction of 2-bromomethyl-1,3-thiaselenole with sodium ethanethiolate in acetonitrile at 20–25°C (2 h) afforded bis[(Z)-2-(vinylsulfanyl)ethenyl] diselenide in 82% yield. The reaction involves intermediate formation of (Z)-1-[(ethylsulfanyl)selanyl]-2-(vinylsulfanyl)ethene.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    S. V. Amosova, A. S. Filippov, V. A. Potapov, M. V. Penzik & A. I. Albanov

Authors
  1. S. V. Amosova
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  2. A. S. Filippov
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  3. V. A. Potapov
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  4. M. V. Penzik
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  5. A. I. Albanov
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Corresponding author

Correspondence to S. V. Amosova.

Additional information

Original Russian Text © S.V. Amosova, A.S. Filippov, V.A. Potapov, M.V. Penzik, A.I. Albanov, 2017, published in Zhurnal Organicheskoi Khimii, 2017, Vol. 53, No. 12, pp. 1842–1844.

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Amosova, S.V., Filippov, A.S., Potapov, V.A. et al. Unexpected reaction of 2-bromomethyl-1,3-thiaselenole with formation of bis[(Z)-2-(vinylsulfanyl)ethenyl] diselenide. Russ J Org Chem 53, 1878–1880 (2017). https://doi.org/10.1134/S1070428017120168

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  • DOI: https://doi.org/10.1134/S1070428017120168

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