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Regio- and stereoselective addition of tellurium tetrachloride to methyl propargyl ether

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Abstract

Reaction of tellurium tetrachloride with methyl propargyl ether proceeds regio- and stereoselectively to afford a product of anti-addition against the Markovnikoff’s rule in quantitative yield. The obtained compound was reduced by sodium metabisulfite into E,E-bis(3-methoxy-1-chloroprop-1-en-2-yl)ditellane.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    M. V. Musalova, A. G. Khabibulina, M. V. Musalov, V. A. Potapov & S. V. Amosova

Authors
  1. M. V. Musalova
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  2. A. G. Khabibulina
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  3. M. V. Musalov
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  4. V. A. Potapov
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  5. S. V. Amosova
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Corresponding author

Correspondence to S. V. Amosova.

Additional information

Original Russian Text © M.V. Musalova, A.G. Khabibulina, M.V. Musalov, V.A. Potapov, S.V. Amosova, 2017, published in Zhurnal Organicheskoi Khimii, 2017, Vol. 53, No. 8, pp. 1251–1252.

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Musalova, M.V., Khabibulina, A.G., Musalov, M.V. et al. Regio- and stereoselective addition of tellurium tetrachloride to methyl propargyl ether. Russ J Org Chem 53, 1268–1269 (2017). https://doi.org/10.1134/S1070428017080188

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  • DOI: https://doi.org/10.1134/S1070428017080188

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