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Desilatranation of 1-organylsilatranes

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Abstract

Reaction of phenyltrifluorosilane with 1-hydro- and 1-ethoxysilatranes proceeds with the cleavage of the F–Si bond and the formation of 1-fluorosilatrane. Under the action of alkylsilatranes also the cleavage of C–Si bond is observed with the formation of a minor product, 1-fluorosilatrane.

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References

  1. Eaborn, C. and Bott, R.W., Organometallic Compounds of the Group IV Elements, MacDiarmid, A.G., Ed., New York: Marcel Dekker, Inc., 1968, vol. 1, Pt. 1.

  2. Eaborn, C., Pure Appl. Chem., 1969, vol. 19, p. 375. doi 10.1351/pac196919030375

    Article  Google Scholar 

  3. Eaborn, C., J. Organometal. Chem., 1975, vol. 100, p. 43. doi 10.1016/S0022-328X(00)88933-0

    Article  CAS  Google Scholar 

  4. Voronkov, M.G., Trofimova, O.M., Chernov, N.F., Albanov, A.I., Chipanina, N.N., and Grebneva, E.A., Appl. Organometal. Chem., 2005, vol. 19, p. 538. doi 10.1002/aoc.861

    Article  CAS  Google Scholar 

  5. Voronkov, M.G., Grebneva, E.A., Trofimova, O.M., Chernov, N.F., Albanov, A.I., and Chipanina, N.N., Dokl. Chem., 2006, vol. 409, p. 139. doi 10.1134/S0012500806080040

    Article  CAS  Google Scholar 

  6. Voronkov, M.G., Albanov, A.I., Grebneva, E.A., Trofimova, O.M., Chernov, N.F., and Chipanina, N.N., Russ. J. Gen. Chem., 2006, vol. 76, p. 1854. doi 10.1134/S1070363206120024

    Article  CAS  Google Scholar 

  7. Korlyukov, A.A., Lyssenko, K.A., Antipin, M.Yu., Grebneva, E.A., Albanov, A.I., Trofimova, O.M., Zel’bst, E.A., and Voronkov, M.G., J. Organometal. Chem., 2009, vol. 694, p. 607. doi 10.1016/j.jorganchem.2008.09.010

    Article  CAS  Google Scholar 

  8. Voronkov, M.G. and D’yakov, V.M., Silatrany (Silatranes), Novosibirsk Nauka, 1978.

    Google Scholar 

  9. Voronkov, M.G., Shevchenko, S.G., Brodskaya, E.I., Baryshok, V.P., D’yakov, V.M., Frolov, Yu.L., Raikh, P., and Anisimova, I.L., Atlas spektrov organicheskikh soedinenii. IK i KRspektry silatranov i model’nykh soedinenii (Atlas of Spectra of Organic Compounds. IR and Raman Spectra Silatranes and Model Compounds), Novosibirsk: Izd. IOKh SOAN SSSR, 1985, vol. 31.

  10. Pestunovich, V., Kirpichenko, S., and Voronkov, M., The Chemistry of Organic Silicon Compounds, Rappoport, Z. and Apeloig, Y., Eds., Chichester: Wiley, 1998, vol. 2, p. 1447.

    Article  CAS  Google Scholar 

  11. Belaventsev, M.A. and Zaleskin, V.V., USSR Inventor’s Certificate no. 300470, 1971; Byull. Izobret., 1971, no. 13.

  12. Gel’man, N.E., Terent’eva, E.A., Shanina, T.M., Kiparenko, L.M., and Rezl, V., Metody kolichestvennogo organicheskogo elementnogo mikroanaliza (The Methods of Quantitative Organic Elemental Microanalysis), Moscow Khimiya, 1987.

    Google Scholar 

  13. Ponomarenko, V.A., Snegova, A.D., and Egorov, Yu.P., Russ. Chem. Bull., 1960, vol. 9, p. 222. doi 10.1007/BF00942894

    Article  Google Scholar 

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    E. A. Grebneva, Yu. I. Bolgova & O. M. Trofimova

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  1. E. A. Grebneva
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  2. Yu. I. Bolgova
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  3. O. M. Trofimova
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Correspondence to O. M. Trofimova.

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Original Russian Text © E.A. Grebneva, Yu.I. Bolgova, O.M. Trofimova, 2017, published in Zhurnal Organicheskoi Khimii, 2017, Vol. 53, No. 2, pp. 307–309.

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Grebneva, E.A., Bolgova, Y.I. & Trofimova, O.M. Desilatranation of 1-organylsilatranes. Russ J Org Chem 53, 309–311 (2017). https://doi.org/10.1134/S1070428017020312

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  • DOI: https://doi.org/10.1134/S1070428017020312

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