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Regiospecific allyl chlorination of betulin and diacetylbetulin

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Abstract

For the first time it was established that in the reaction of selenium dichloride with betulin and diacetylbetulin it is realized regiospecific allylic substitution of hydrogen in these alkenes by chlorine atom with formation of a single product–an unsaturated chloride of allylic type. The structure of products was proved by 1Н NMR spectra.

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Authors and Affiliations

  1. Nizhny Novgorod State Technical University n. a. R.E. Alekseev, ul. Minina 24, Nizhny Novgorod, 603950, Russia

    Yu. A. Kurskii, I. V. Bodrikov & L. I. Bazhan

  2. G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

    Yu. A. Kurskii

  3. Lobachevsky State University of Nizhny Novgorod, Nizhny Novgorod, Russia

    A. A. Chiyanov

Authors
  1. Yu. A. Kurskii
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  2. I. V. Bodrikov
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  3. A. A. Chiyanov
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  4. L. I. Bazhan
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Corresponding author

Correspondence to L. I. Bazhan.

Additional information

Original Russian Text © Yu.A. Kurskii, I.V. Bodrikov, A.A. Chiyanov, L.I. Bazhan, 2017, published in Zhurnal Organicheskoi Khimii, 2017, Vol. 53, No. 2, pp. 301–302.

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Kurskii, Y.A., Bodrikov, I.V., Chiyanov, A.A. et al. Regiospecific allyl chlorination of betulin and diacetylbetulin. Russ J Org Chem 53, 303–304 (2017). https://doi.org/10.1134/S1070428017020294

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  • DOI: https://doi.org/10.1134/S1070428017020294

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