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Selective hydroxylation of diamantane with 2,3,4,5,6-pentafluoroperbenzoic acid in the presence of molibdenum complexes

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Abstract

Oxidation of diamantane with 2,3,4,5,6-pentafluoroperbenzoic acid catalyzed with complexes MoO(O2)·2QOH, MoO(O2)(H2O)2 proceeds selectively affording diamantan-1-ol and diamantan-1-yl 2,3,4,5,6-pentafluorobenzoate.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, Ufa, 450075, Russia

    R. I. Khusnutdinov, T. M. Oshnyakova, L. M. Khalilov, A. R. Baibuldina & U. M. Dzhemilev

Authors
  1. R. I. Khusnutdinov
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  2. T. M. Oshnyakova
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  3. L. M. Khalilov
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  4. A. R. Baibuldina
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  5. U. M. Dzhemilev
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Correspondence to U. M. Dzhemilev.

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Original Russian Text © R.I. Khusnutdinov, T.M. Oshnyakova, L.M. Khalilov, A.R. Baibuldina, U.M. Dzhemilev, 2016, published in Zhurnal Organicheskoi Khimii, 2016, Vol. 52, No. 8, pp. 1131–1135.

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Khusnutdinov, R.I., Oshnyakova, T.M., Khalilov, L.M. et al. Selective hydroxylation of diamantane with 2,3,4,5,6-pentafluoroperbenzoic acid in the presence of molibdenum complexes. Russ J Org Chem 52, 1121–1125 (2016). https://doi.org/10.1134/S1070428016080054

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  • DOI: https://doi.org/10.1134/S1070428016080054

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