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Synthesis of (–)-(3aR,4R,5S,6aS)-4-[(acetoxy)methyl]-1-oxohexahydro-1H-cyclopenta[c]furan-5-yl Acetate

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Abstract

A new 1,2,3,4-functionalized cyclopentane, (–)-(3aR,4R,5S,6aS)-4-[(acetoxy)methyl]-1-oxohexahydro-1H-cyclopenta[c]furan-5-yl acetate, has been synthesized by cleavage of a tricyclic bowl-shaped aminal, (2aR,3S,4aS,6bR)-3-hydroxy-6-[(1R)-1-phenylethyl]-octahydro-5H-1-oxa-6-azacyclopenta[cd]pentalen-5-one.

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Authors and Affiliations

  1. Institute of Chemistry, Russian Academy of Sciences, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054, Russia

    A. M. Gimazetdinov, V. V. Loza, A. Z. Al’mukhametov & M. S. Miftakhov

Authors
  1. A. M. Gimazetdinov
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  2. V. V. Loza
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  3. A. Z. Al’mukhametov
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  4. M. S. Miftakhov
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Corresponding author

Correspondence to A. M. Gimazetdinov.

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Original Russian Text © A.M. Gimazetdinov, V.V. Loza, A.Z. Al’mukhametov, M.S. Miftakhov, 2016, published in Zhurnal Organicheskoi Khimii, 2016, Vol. 52, No. 4, pp. 537–539.

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Gimazetdinov, A.M., Loza, V.V., Al’mukhametov, A.Z. et al. Synthesis of (–)-(3aR,4R,5S,6aS)-4-[(acetoxy)methyl]-1-oxohexahydro-1H-cyclopenta[c]furan-5-yl Acetate. Russ J Org Chem 52, 523–525 (2016). https://doi.org/10.1134/S1070428016040072

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  • DOI: https://doi.org/10.1134/S1070428016040072

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