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Synthesis and spectral properties of lutetium sandwich complexes containing fragments of tetrabenzoporphyrin and alkoxy(chloro)-substituted phthalocyanines of low symmetry

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Abstract

Joint condensation of 3,6-dioctyloxyphthalonitrile (component A) and tetrachlorophthalonitrile (component B) in 1-hexanol in the presence of lithium 1-hexanolate afforded dilithium complexes of phthalocyanines A3B, AABB, and ABAB. Their reaction with chlorolutetium tetrabenzoporphyrinate resulted in the formation of double-decker heteroligand lutetium complexes containing chromophores of tetrabenzoporphyrin and phthalocyanines of low symmetry.

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References

  1. Nicholson, M.M., Phthalocyanines-Properties and Applications, Leznoff, C.C., Lever, A.B.P., Eds., New York: VCH Publ. Inc., 1993, vol. 3.

  2. Andre, J.J., Holezer, K., Petit, P., Riou, M.T., Clarisse, C., Even, R., Fourmigue, M., and Simon, J., Chem. Phys. Lett., 1985, vol. 115, p. 463.

    Article  CAS  Google Scholar 

  3. Turek, P., Petit, P., Andre, J.J., Simon, J., Even, R., Boudjema, B., Guillaud, G., and Maitrot, M., J. Am. Chem. Soc., 1987, vol. 109, p. 5119.

    Article  CAS  Google Scholar 

  4. Maitrot, M., Guillaud, G., Boudjema, B., Andre, J.J., Strzelecka, H., Simon, J., and Even, R., Chem. Phys. Lett., 1987, vol. 133, p. 59.

    Article  CAS  Google Scholar 

  5. Souto, J., Rodriguez, M.L., Desaja, J.A., and Aroca, R., Int. J. Electron, 1994, vol. 76, p. 763.

    Article  CAS  Google Scholar 

  6. Buchler, J.W., Elsässer, K., Kihn-Botulinski, M., and Scharbert, B., Angew. Chem., Int. Ed., 1986, vol. 25, p. 286.

    Article  Google Scholar 

  7. Buchler, J.W., Comm. Inorg. Chem., 1987, vol. 6, p. 175.

    Article  CAS  Google Scholar 

  8. Buchler, J.W. and Nawra, M., Inorg. Chem., 1994, vol. 33, p. 2830.

    Article  CAS  Google Scholar 

  9. Jiang, J., Xie, J., Choi, M.T.M., Yan, Y., Sun, S., and Ng, D.K.P., J. Porph. Phthal., 1999, vol. 3, p. 322.

    Article  CAS  Google Scholar 

  10. Jiang, J., Choi, M.T.M., Law, W.F., Chen, J., and Ng, D.K.P., Polyhedron, 1998, vol. 17, p. 3903.

    Article  CAS  Google Scholar 

  11. Bai, M., Bao, M., Ma, C., Arnold, D.P., Choi, M.T.M., Ng, D.K.P., and Jiang, J., J. Mater. Chem., 2003, vol. 13, p. 1333.

    Article  CAS  Google Scholar 

  12. Birin, K.P., Gorbunova, Yu.G., and Tsivadze, A.Yu., Macroheterocycles, 2010, vol. 3, p. 210.

    CAS  Google Scholar 

  13. Kudrik, E.V., Islyaikin, M.K., and Shaposhnikov, G.P., Russ. J. Gen. Chem., 2000, vol. 70, p. 767.

    CAS  Google Scholar 

  14. Galanin, N.E., Yakubov, L.A., and Shaposhnikov, G.P., Russ. J. Org. Chem., 2008, vol. 44, p. 921.

    Article  CAS  Google Scholar 

  15. Galanin, N.E. and Shaposhnikov, G.P., Russ. J. Gen. Chem., 2012, vol. 82, p. 764.

    Article  CAS  Google Scholar 

  16. Kopranenkov, V.N., Makarova, E.A., and Luk’yanets, E.A., Chem. Heterocycl. Compd., 1988, vol. 24, p. 394.

    Article  Google Scholar 

  17. Galanin, N.E. and Shaposhnikov, G.P., Russ. J. Org. Chem., 2012, vol. 48, p. 851.

    Article  CAS  Google Scholar 

  18. Galanin, N.E. and Shaposhnikov, G.P., Russ. J. Gen. Chem., 2012, vol. 82, p. 1734.

    Article  CAS  Google Scholar 

  19. Vinogradov, S.A. and Wilson, D.F., J. Chem. Soc., Perkin Trans. 2, 1995, p. 103.

    Google Scholar 

  20. Kobayashi, N. and Konami, H., Phthalocyanines: Properties and Applications, Leznoff, C.C., Lever, A.B.P., Eds., New York: VCH Publishers Inc., 1996, vol. 4.

  21. Moskalev, P.N. and Kirin, I.S., Zh. Fiz. Khim., 1972, vol. 46, p. 1778.

    CAS  Google Scholar 

  22. Moskalev, P.N., Sibilev, A.I., and Sedov, V.P., Elektrokhimiya, 1988, vol. 24, p. 1319.

    CAS  Google Scholar 

  23. Kandaz, M., Bilgicli, A.T., and Altindal, A., Synth. Met., 2010, vol. 160, p. 52.

    Article  CAS  Google Scholar 

  24. Pushkarev, V.E., Tolbin, A.Yu., Borisova, N.E., Trashin, S.A., and Tomilova, L.G., Eur. J. Inorg. Chem., 2010, p. 5254.

    Google Scholar 

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Authors and Affiliations

  1. Research Institute of Macroheterocyclic Compounds, Ivanovo State University of Chemical Technology, Sheremetevskii pr. 7, Ivanovo, 153000, Russia

    N. E. Galanin & G. P. Shaposhnikov

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  1. N. E. Galanin
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  2. G. P. Shaposhnikov
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Correspondence to N. E. Galanin.

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Original Russian Text © N.E. Galanin, G.P. Shaposhnikov, 2015, published in Zhurnal Organicheskoi Khimii, 2015, Vol. 51, No. 5, pp. 743–748.

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Galanin, N.E., Shaposhnikov, G.P. Synthesis and spectral properties of lutetium sandwich complexes containing fragments of tetrabenzoporphyrin and alkoxy(chloro)-substituted phthalocyanines of low symmetry. Russ J Org Chem 51, 727–732 (2015). https://doi.org/10.1134/S1070428015050243

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  • DOI: https://doi.org/10.1134/S1070428015050243

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